Publications by Department of Nonlinear Optics
Departments of ISQI | Publications of ISQI
2024 |
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| 81. | Xin Wang, Jia-Qi Li, Tao Liu, Adam Miranowicz, Franco Nori Long-range four-body interactions in structured nonlinear photonic waveguides Phys. Rev. Res., 6 , pp. 043226, 2024. @article{Wang24prr, title = {Long-range four-body interactions in structured nonlinear photonic waveguides}, author = {Xin Wang and Jia-Qi Li and Tao Liu and Adam Miranowicz and Franco Nori}, url = {https://link.aps.org/doi/10.1103/PhysRevResearch.6.043226}, doi = {10.1103/PhysRevResearch.6.043226}, year = {2024}, date = {2024-12-01}, journal = {Phys. Rev. Res.}, volume = {6}, pages = {043226}, publisher = {American Physical Society}, keywords = {}, pubstate = {published}, tppubtype = {article} } |
| 80. | Shilan Abo, Patrycja Tulewicz, Karol Bartkiewicz, Şahin K Özdemir, Adam Miranowicz Experimental Liouvillian exceptional points in a quantum system without Hamiltonian singularities New Journal of Physics, 26 (12), pp. 123032, 2024. @article{Abo_2024, title = {Experimental Liouvillian exceptional points in a quantum system without Hamiltonian singularities}, author = {Shilan Abo and Patrycja Tulewicz and Karol Bartkiewicz and Şahin K Özdemir and Adam Miranowicz}, url = {https://dx.doi.org/10.1088/1367-2630/ad98b6}, doi = {10.1088/1367-2630/ad98b6}, year = {2024}, date = {2024-12-01}, journal = {New Journal of Physics}, volume = {26}, number = {12}, pages = {123032}, publisher = {IOP Publishing}, abstract = {Hamiltonian exceptional points (HEPs) are spectral degeneracies of non-Hermitian Hamiltonians describing classical and semiclassical open systems with losses and/or gain. However, this definition overlooks the occurrence of quantum jumps in the evolution of open quantum systems. These quantum effects are properly accounted for by considering quantum Liouvillians and their exceptional points (LEPs). Specifically, an LEP corresponds to the coalescence of two or more eigenvalues and the corresponding eigenmatrices of a given Liouvillian at critical values of external parameters (Minganti et al 2019 Phys. Rev. A 100 062131). Here, we explicitly describe how standard quantum process tomography, which reveals the dynamics of a quantum system, can be readily applied to detect and characterize quantum LEPs of quantum non-Hermitian systems. We conducted experiments on an IBM quantum processor to implement a prototype model with one-, two-, and three qubits simulating the decay of a single qubit through competing channels, resulting in LEPs but not HEPs. Subsequently, we performed tomographic reconstruction of the corresponding experimental Liouvillian and its LEPs using both single- and two-qubit operations. This example underscores the efficacy of process tomography in tuning and observing LEPs even in the absence of HEPs.}, keywords = {}, pubstate = {published}, tppubtype = {article} } Hamiltonian exceptional points (HEPs) are spectral degeneracies of non-Hermitian Hamiltonians describing classical and semiclassical open systems with losses and/or gain. However, this definition overlooks the occurrence of quantum jumps in the evolution of open quantum systems. These quantum effects are properly accounted for by considering quantum Liouvillians and their exceptional points (LEPs). Specifically, an LEP corresponds to the coalescence of two or more eigenvalues and the corresponding eigenmatrices of a given Liouvillian at critical values of external parameters (Minganti et al 2019 Phys. Rev. A 100 062131). Here, we explicitly describe how standard quantum process tomography, which reveals the dynamics of a quantum system, can be readily applied to detect and characterize quantum LEPs of quantum non-Hermitian systems. We conducted experiments on an IBM quantum processor to implement a prototype model with one-, two-, and three qubits simulating the decay of a single qubit through competing channels, resulting in LEPs but not HEPs. Subsequently, we performed tomographic reconstruction of the corresponding experimental Liouvillian and its LEPs using both single- and two-qubit operations. This example underscores the efficacy of process tomography in tuning and observing LEPs even in the absence of HEPs. |
| 79. | Wei Qin, Adam Miranowicz, Franco Nori Exponentially Improved Dispersive Qubit Readout with Squeezed Light Phys. Rev. Lett., 133 , pp. 233605, 2024. @article{Wei2024prr, title = {Exponentially Improved Dispersive Qubit Readout with Squeezed Light}, author = {Wei Qin and Adam Miranowicz and Franco Nori}, url = {https://link.aps.org/doi/10.1103/PhysRevLett.133.233605}, doi = {10.1103/PhysRevLett.133.233605}, year = {2024}, date = {2024-12-01}, journal = {Phys. Rev. Lett.}, volume = {133}, pages = {233605}, publisher = {American Physical Society}, keywords = {}, pubstate = {published}, tppubtype = {article} } |
| 78. | Wanhua Su, Wei Qin, Adam Miranowicz, Tao Li, Franco Nori Heralded nonlocal quantum gates for distributed quantum computation in a decoherence-free subspace Phys. Rev. A, 110 , pp. 052612, 2024. @article{Su2024pra, title = {Heralded nonlocal quantum gates for distributed quantum computation in a decoherence-free subspace}, author = {Wanhua Su and Wei Qin and Adam Miranowicz and Tao Li and Franco Nori}, url = {https://link.aps.org/doi/10.1103/PhysRevA.110.052612}, doi = {10.1103/PhysRevA.110.052612}, year = {2024}, date = {2024-11-01}, journal = {Phys. Rev. A}, volume = {110}, pages = {052612}, publisher = {American Physical Society}, keywords = {}, pubstate = {published}, tppubtype = {article} } |
| 77. | Ievgen I Arkhipov, Fabrizio Minganti, Adam Miranowicz, Sahin K Özdemir, Franco Nori Restoring Adiabatic State Transfer in Time-Modulated Non-Hermitian Systems Phys. Rev. Lett., 133 , pp. 113802, 2024. @article{Arkhipov24prl, title = {Restoring Adiabatic State Transfer in Time-Modulated Non-Hermitian Systems}, author = {Ievgen I Arkhipov and Fabrizio Minganti and Adam Miranowicz and Sahin K Özdemir and Franco Nori}, url = {https://link.aps.org/doi/10.1103/PhysRevLett.133.113802}, doi = {10.1103/PhysRevLett.133.113802}, year = {2024}, date = {2024-09-01}, journal = {Phys. Rev. Lett.}, volume = {133}, pages = {113802}, publisher = {American Physical Society}, keywords = {}, pubstate = {published}, tppubtype = {article} } |
| 76. | Josef Kadlec, Karol Bartkiewicz, Antonín Černoch, Karel Lemr, Adam Miranowicz Experimental relative entanglement potentials of single-photon states Phys. Rev. A, 110 , pp. 023720, 2024. @article{PhysRevA.110.023720, title = {Experimental relative entanglement potentials of single-photon states}, author = {Josef Kadlec and Karol Bartkiewicz and Antonín Černoch and Karel Lemr and Adam Miranowicz}, url = {https://link.aps.org/doi/10.1103/PhysRevA.110.023720}, doi = {10.1103/PhysRevA.110.023720}, year = {2024}, date = {2024-08-01}, journal = {Phys. Rev. A}, volume = {110}, pages = {023720}, publisher = {American Physical Society}, keywords = {}, pubstate = {published}, tppubtype = {article} } |
| 75. | Vojtiěch Trávníček, Jan Roik, Karol Bartkiewicz, Antonín Černoch, Paweł Horodecki, Karel Lemr Sensitivity versus selectivity in entanglement detection via collective witnesses Phys. Rev. Res., 6 , pp. 033056, 2024. @article{PhysRevResearch.6.033056, title = {Sensitivity versus selectivity in entanglement detection via collective witnesses}, author = {Vojtiěch Trávníček and Jan Roik and Karol Bartkiewicz and Antonín Černoch and Paweł Horodecki and Karel Lemr}, url = {https://link.aps.org/doi/10.1103/PhysRevResearch.6.033056}, doi = {10.1103/PhysRevResearch.6.033056}, year = {2024}, date = {2024-07-01}, journal = {Phys. Rev. Res.}, volume = {6}, pages = {033056}, publisher = {American Physical Society}, keywords = {}, pubstate = {published}, tppubtype = {article} } |
| 74. | Anna Jelec, Karol Bartkiewicz, Katarzyna Stachowiak-Szymczak, Joanna Ziobro-Strzępek Why not(es)? Automatic analysis of notes for consecutive interpreting training Biernacka Agnieszka, Figiel Wojciech (Ed.): 18 (12), pp. 245-268, Peter Lang Verlag, Berlin, Bruxelles, Chennai, Lausanne, New York, Oxford, 2024, ISBN: 9783631907122. @inbook{UAM3e12f04642694835a7c486a6658d9b64, title = {Why not(es)? Automatic analysis of notes for consecutive interpreting training}, author = {Anna Jelec and Karol Bartkiewicz and Katarzyna Stachowiak-Szymczak and Joanna Ziobro-Strzępek}, editor = {Biernacka Agnieszka, Figiel Wojciech}, url = {https://www.peterlang.com/document/1370692}, doi = {10.3726/b21104}, isbn = {9783631907122}, year = {2024}, date = {2024-07-01}, journal = {Phys. Rev. Res.}, volume = {18}, number = {12}, pages = {245-268}, publisher = {Peter Lang Verlag}, address = {Berlin, Bruxelles, Chennai, Lausanne, New York, Oxford}, series = {Studies in Language, Culture and Society: New Insights into Interpreting Studies}, abstract = {This volume is a collective work of eighteen eminent researchers representing various sub-fields of Interpreting Studies who contribute with fourteen chapters. The topics include various areas and approaches: interpreting from a philosophical, sociological and historical perspective, ethics of interpreters, court interpreting, public service interpreting, signed language interpreting, interpreting for minors and for refugees and asylum seekers, note-taking in consecutive interpreting, accessibility, as well as technology in interpreting and interpreter training. The multiplicity of themes and the multifaceted nature of the research prove that Interpreting Studies is nowadays a field that combines different disciplines and methodologies.}, type = {book}, keywords = {}, pubstate = {published}, tppubtype = {inbook} } This volume is a collective work of eighteen eminent researchers representing various sub-fields of Interpreting Studies who contribute with fourteen chapters. The topics include various areas and approaches: interpreting from a philosophical, sociological and historical perspective, ethics of interpreters, court interpreting, public service interpreting, signed language interpreting, interpreting for minors and for refugees and asylum seekers, note-taking in consecutive interpreting, accessibility, as well as technology in interpreting and interpreter training. The multiplicity of themes and the multifaceted nature of the research prove that Interpreting Studies is nowadays a field that combines different disciplines and methodologies. |
| 73. | Deng-Gao Lai, Adam Miranowicz, Franco Nori Phys. Rev. Lett., 132 , pp. 243602, 2024. @article{Lai24prl, title = {Nonreciprocal Topological Phonon Transfer Independent of Both Device Mass and Exceptional-Point Encircling Direction}, author = {Deng-Gao Lai and Adam Miranowicz and Franco Nori}, url = {https://link.aps.org/doi/10.1103/PhysRevLett.132.243602}, doi = {10.1103/PhysRevLett.132.243602}, year = {2024}, date = {2024-06-01}, journal = {Phys. Rev. Lett.}, volume = {132}, pages = {243602}, publisher = {American Physical Society}, keywords = {}, pubstate = {published}, tppubtype = {article} } |
| 72. | Yunlan Zuo, Ya-Feng Jiao, Xun-Wei Xu, Adam Miranowicz, Le-Man Kuang, Hui Jing Chiral photon blockade in the spinning Kerr resonator Opt. Express, 32 (12), pp. 22020–22030, 2024. @article{Zuo2024, title = {Chiral photon blockade in the spinning Kerr resonator}, author = {Yunlan Zuo and Ya-Feng Jiao and Xun-Wei Xu and Adam Miranowicz and Le-Man Kuang and Hui Jing}, url = {https://opg.optica.org/oe/abstract.cfm?URI=oe-32-12-22020}, doi = {10.1364/OE.524680}, year = {2024}, date = {2024-06-01}, journal = {Opt. Express}, volume = {32}, number = {12}, pages = {22020--22030}, publisher = {Optica Publishing Group}, abstract = {We propose how to achieve chiral photon blockade by spinning a nonlinear optical resonator. We show that by driving such a device at a fixed direction, completely different quantum effects can emerge for the counter-propagating optical modes, due to the spinning-induced breaking of time-reversal symmetry, which otherwise is unattainable for the same device in the static regime. Also, we find that in comparison with the static case, robust non-classical correlations against random backscattering losses can be achieved for such a quantum chiral system. Our work, extending previous works on the spontaneous breaking of optical chiral symmetry from the classical to purely quantum regimes, can stimulate more efforts towards making and utilizing various chiral quantum effects, including applications for chiral quantum networks or noise-tolerant quantum sensors.}, keywords = {}, pubstate = {published}, tppubtype = {article} } We propose how to achieve chiral photon blockade by spinning a nonlinear optical resonator. We show that by driving such a device at a fixed direction, completely different quantum effects can emerge for the counter-propagating optical modes, due to the spinning-induced breaking of time-reversal symmetry, which otherwise is unattainable for the same device in the static regime. Also, we find that in comparison with the static case, robust non-classical correlations against random backscattering losses can be achieved for such a quantum chiral system. Our work, extending previous works on the spontaneous breaking of optical chiral symmetry from the classical to purely quantum regimes, can stimulate more efforts towards making and utilizing various chiral quantum effects, including applications for chiral quantum networks or noise-tolerant quantum sensors. |
| 71. | Deng-Gao Lai, C -H Wang, B -P Hou, Adam Miranowicz, Franco Nori Exceptional refrigeration of motions beyond their mass and temperature limitations Optica, 11 (4), pp. 485–491, 2024. @article{Lai2024b, title = {Exceptional refrigeration of motions beyond their mass and temperature limitations}, author = {Deng-Gao Lai and C -H Wang and B -P Hou and Adam Miranowicz and Franco Nori}, url = {https://opg.optica.org/optica/abstract.cfm?URI=optica-11-4-485}, doi = {10.1364/OPTICA.495199}, year = {2024}, date = {2024-04-01}, journal = {Optica}, volume = {11}, number = {4}, pages = {485--491}, publisher = {Optica Publishing Group}, abstract = {Coaxing vibrations in the regimes of both large mass and high temperature into their motional quantum ground states is extremely challenging, because it requires an ultra-high optical power, which introduces extraneous excessive heating and intricate instabilities. Here we propose how to overcome these obstacles and cool vibrational networks by simply harnessing the power of an exceptional point (EP) induced in parity-time symmetric structures; and we reveal its exceptional cooling properties otherwise unachievable in conventional devices. In stark contrast to standard-cooling protocols, a three orders-of-magnitude amplification in net cooling rates arises from the EP-cooling mechanism, without which it vanishes. Remarkably, our EP cooling is nearly immune to both resonator mass and environmental temperature, and this overthrows the consensus that poor intrinsic factors and rugged extrinsic environment suppress cooling channels. Our study offers the possibility of isolating and engineering motional properties of large-mass and high-temperature objects for various applications in optical and acoustic sensing, gravimetry, and inertial navigation.}, keywords = {}, pubstate = {published}, tppubtype = {article} } Coaxing vibrations in the regimes of both large mass and high temperature into their motional quantum ground states is extremely challenging, because it requires an ultra-high optical power, which introduces extraneous excessive heating and intricate instabilities. Here we propose how to overcome these obstacles and cool vibrational networks by simply harnessing the power of an exceptional point (EP) induced in parity-time symmetric structures; and we reveal its exceptional cooling properties otherwise unachievable in conventional devices. In stark contrast to standard-cooling protocols, a three orders-of-magnitude amplification in net cooling rates arises from the EP-cooling mechanism, without which it vanishes. Remarkably, our EP cooling is nearly immune to both resonator mass and environmental temperature, and this overthrows the consensus that poor intrinsic factors and rugged extrinsic environment suppress cooling channels. Our study offers the possibility of isolating and engineering motional properties of large-mass and high-temperature objects for various applications in optical and acoustic sensing, gravimetry, and inertial navigation. |
| 70. | Chia-Yi Ju, Adam Miranowicz, Yueh-Nan Chen, Guang-Yin Chen, Franco Nori Emergent parallel transport and curvature in Hermitian and non-Hermitian quantum mechanics Quantum, 8 , pp. 1277, 2024. @article{Ju2024, title = {Emergent parallel transport and curvature in Hermitian and non-Hermitian quantum mechanics}, author = {Chia-Yi Ju and Adam Miranowicz and Yueh-Nan Chen and Guang-Yin Chen and Franco Nori}, url = {https://quantum-journal.org/papers/q-2024-03-13-1277/}, doi = {10.22331/q-2024-03-13-1277}, year = {2024}, date = {2024-03-13}, journal = {Quantum}, volume = {8}, pages = {1277}, abstract = {Studies have shown that the Hilbert spaces of non-Hermitian systems require nontrivial metrics. Here, we demonstrate how evolution dimensions, in addition to time, can emerge naturally from a geometric formalism. Specifically, in this formalism, Hamiltonians can be interpreted as a Christoffel symbol-like operators, and the Schroedinger equation as a parallel transport in this formalism. We then derive the evolution equations for the states and metrics along the emergent dimensions and find that the curvature of the Hilbert space bundle for any given closed system is locally flat. Finally, we show that the fidelity susceptibilities and the Berry curvatures of states are related to these emergent parallel transports.}, keywords = {}, pubstate = {published}, tppubtype = {article} } Studies have shown that the Hilbert spaces of non-Hermitian systems require nontrivial metrics. Here, we demonstrate how evolution dimensions, in addition to time, can emerge naturally from a geometric formalism. Specifically, in this formalism, Hamiltonians can be interpreted as a Christoffel symbol-like operators, and the Schroedinger equation as a parallel transport in this formalism. We then derive the evolution equations for the states and metrics along the emergent dimensions and find that the curvature of the Hilbert space bundle for any given closed system is locally flat. Finally, we show that the fidelity susceptibilities and the Berry curvatures of states are related to these emergent parallel transports. |
| 69. | Arnab Laha, Adam Miranowicz, R. K. Varshney, Somnath Ghosh Correlated nonreciprocity around conjugate exceptional points Phys. Rev. A, 109 , pp. 033511, 2024. @article{Laha2024, title = {Correlated nonreciprocity around conjugate exceptional points}, author = {Arnab Laha and Adam Miranowicz and R. K. Varshney and Somnath Ghosh}, url = {https://link.aps.org/doi/10.1103/PhysRevA.109.033511}, doi = {10.1103/PhysRevA.109.033511}, year = {2024}, date = {2024-03-08}, journal = {Phys. Rev. A}, volume = {109}, pages = {033511}, abstract = {The occurrence of exceptional points (EPs) is a fascinating non-Hermitian feature of open systems. A level-repulsion phenomenon between two complex states of an open system can be realized by positioning an EP and its time-reversal ( T ) conjugate pair in the underlying parameter space. Here, we report interesting nonreciprocal responses of such two conjugate EPs by using a dual-mode planar waveguide system having two T -symmetric active variants concerning the transverse gain-loss profiles. We specifically reveal an all-optical scheme to achieve correlative nonreciprocal light dynamics by using the reverse chirality of two dynamically encircled conjugate EPs in the presence of local nonlinearity. A specific nonreciprocal correlation between two designed T -symmetric waveguide variants is established in terms of their unidirectional transfer of light with a precise selection of modes. Here, the unconventional reverse chiral properties of two conjugate EPs allow the nonreciprocal transmission of two selective modes in the opposite directions of the underlying waveguide variants. An explicit dependence of the nonlinearity level on a significant enhancement of the nonreciprocity in terms of an isolation ratio is explored by investigating the effects of both local Kerr-type and saturable nonlinearities (considered separately). The physical insights and implications of harnessing the features of conjugate EPs in nonlinear optical systems can enable the growth and development of a versatile platform for building nonreciprocal components and devices.}, keywords = {}, pubstate = {published}, tppubtype = {article} } The occurrence of exceptional points (EPs) is a fascinating non-Hermitian feature of open systems. A level-repulsion phenomenon between two complex states of an open system can be realized by positioning an EP and its time-reversal ( T ) conjugate pair in the underlying parameter space. Here, we report interesting nonreciprocal responses of such two conjugate EPs by using a dual-mode planar waveguide system having two T -symmetric active variants concerning the transverse gain-loss profiles. We specifically reveal an all-optical scheme to achieve correlative nonreciprocal light dynamics by using the reverse chirality of two dynamically encircled conjugate EPs in the presence of local nonlinearity. A specific nonreciprocal correlation between two designed T -symmetric waveguide variants is established in terms of their unidirectional transfer of light with a precise selection of modes. Here, the unconventional reverse chiral properties of two conjugate EPs allow the nonreciprocal transmission of two selective modes in the opposite directions of the underlying waveguide variants. An explicit dependence of the nonlinearity level on a significant enhancement of the nonreciprocity in terms of an isolation ratio is explored by investigating the effects of both local Kerr-type and saturable nonlinearities (considered separately). The physical insights and implications of harnessing the features of conjugate EPs in nonlinear optical systems can enable the growth and development of a versatile platform for building nonreciprocal components and devices. |
| 68. | Wei Qin, Adam Miranowicz, Franco Nori Proposal of ensemble qubits with two-atom decay New Journal of Physics, 26 , pp. 033006, 2024. @article{Qin2024, title = {Proposal of ensemble qubits with two-atom decay}, author = {Wei Qin and Adam Miranowicz and Franco Nori}, url = {https://iopscience.iop.org/article/10.1088/1367-2630/ad2bad}, doi = {10.1088/1367-2630/ad2bad}, year = {2024}, date = {2024-03-08}, journal = {New Journal of Physics}, volume = {26}, pages = {033006}, abstract = {We propose and analyze a novel approach to implement ensemble qubits. The required anharmonicity is provided by a simultaneous decay of two atoms (i.e. two-atom decay), which is achieved by fully quantum degenerate parametric amplification. For an atomic ensemble, the two-atom decay generates and stabilizes a 2D quantum manifold, which is spanned by the ground and single-excited superradiant states. Moreover, this nonlinear decay process can strongly suppress transitions to higher-excited superradiant states, and convert residual transitions into an effective decay from the single-excitation superradiant state to the ground state. Our method does not require Rydberg dipole blockade and, thus, strong atom-atom interactions, compared to previous work. This indicates that it can be applied to typical atomic or spin ensembles in simple experimental setups. Remarkably, our idea is compatible with the cavity protection mechanism, and therefore spin dephasing due to inhomogeneous broadening can be strongly suppressed. The presented ensemble qubit provides a new platform for quantum information processing, and also extends the range of applications of atomic or spin ensembles.}, keywords = {}, pubstate = {published}, tppubtype = {article} } We propose and analyze a novel approach to implement ensemble qubits. The required anharmonicity is provided by a simultaneous decay of two atoms (i.e. two-atom decay), which is achieved by fully quantum degenerate parametric amplification. For an atomic ensemble, the two-atom decay generates and stabilizes a 2D quantum manifold, which is spanned by the ground and single-excited superradiant states. Moreover, this nonlinear decay process can strongly suppress transitions to higher-excited superradiant states, and convert residual transitions into an effective decay from the single-excitation superradiant state to the ground state. Our method does not require Rydberg dipole blockade and, thus, strong atom-atom interactions, compared to previous work. This indicates that it can be applied to typical atomic or spin ensembles in simple experimental setups. Remarkably, our idea is compatible with the cavity protection mechanism, and therefore spin dephasing due to inhomogeneous broadening can be strongly suppressed. The presented ensemble qubit provides a new platform for quantum information processing, and also extends the range of applications of atomic or spin ensembles. |
| 67. | Marek Kopciuch, Magdalena Smolis, Adam Miranowicz, Szymon Pustelny Optimized optical tomography of quantum states of a room-temperature alkali-metal vapor Phys. Rev. A, 109 , pp. 032402, 2024. @article{Kopciuch2024, title = {Optimized optical tomography of quantum states of a room-temperature alkali-metal vapor}, author = {Marek Kopciuch and Magdalena Smolis and Adam Miranowicz and Szymon Pustelny}, url = {https://link.aps.org/doi/10.1103/PhysRevA.109.032402}, doi = {10.1103/PhysRevA.109.032402}, year = {2024}, date = {2024-03-01}, journal = {Phys. Rev. A}, volume = {109}, pages = {032402}, abstract = {We demonstrate an experimental technique for the quantum-state tomography of the collective qutrit states of a room-temperature alkali-metal vapor. It is based on the measurements of the polarization of light traversing the vapor subjected to a magnetic field. To assess the technique's robustness against errors, experimental investigations are supported with numerical simulations. This not only allows us to determine the fidelity of the reconstructed states, but also to analyze the quality of the reconstruction for specific experimental parameters, such as light tuning and the number of measurements. By utilizing the conditional number, we demonstrate that the reconstruction robustness can be optimized by a proper adjustment of experimental parameters, and further improvement is possible with the repetition of specific measurements. Our results demonstrate the potential of this high-fidelity reconstruction method of quantum states of room-temperature atomic vapors.}, keywords = {}, pubstate = {published}, tppubtype = {article} } We demonstrate an experimental technique for the quantum-state tomography of the collective qutrit states of a room-temperature alkali-metal vapor. It is based on the measurements of the polarization of light traversing the vapor subjected to a magnetic field. To assess the technique's robustness against errors, experimental investigations are supported with numerical simulations. This not only allows us to determine the fidelity of the reconstructed states, but also to analyze the quality of the reconstruction for specific experimental parameters, such as light tuning and the number of measurements. By utilizing the conditional number, we demonstrate that the reconstruction robustness can be optimized by a proper adjustment of experimental parameters, and further improvement is possible with the repetition of specific measurements. Our results demonstrate the potential of this high-fidelity reconstruction method of quantum states of room-temperature atomic vapors. |
| 66. | Ye-Hong Chen, Yuan Qiu, Adam Miranowicz, Neill Lambert, Wei Qin, Roberto Stassi, Yan Xia, Shi-Biao Zheng, Franco Nori Sudden change of the photon output field marks phase transitions in the quantum Rabi model Communications Physics, 7 (5), 2024. @article{Chen2024, title = {Sudden change of the photon output field marks phase transitions in the quantum Rabi model}, author = {Ye-Hong Chen and Yuan Qiu and Adam Miranowicz and Neill Lambert and Wei Qin and Roberto Stassi and Yan Xia and Shi-Biao Zheng and Franco Nori}, url = {https://www.nature.com/articles/s42005-023-01457-w}, doi = {10.1038/s42005-023-01457-w}, year = {2024}, date = {2024-01-05}, journal = {Communications Physics}, volume = {7}, number = {5}, abstract = {The experimental observation of quantum phase transitions predicted by the quantum Rabi model in quantum critical systems is usually challenging due to the lack of signature experimental observables associated with them. Here, we describe a method to identify the dynamical critical phenomenon in the quantum Rabi model consisting of a three-level atom and a cavity at the quantum phase transition. Such a critical phenomenon manifests itself as a sudden change of steady-state output photons in the system driven by two classical fields, when both the atom and the cavity are initially unexcited. The process occurs as the high-frequency pump field is converted into the low-frequency Stokes field and multiple cavity photons in the normal phase, while this conversion cannot occur in the superradiant phase. The sudden change of steady-state output photons is an experimentally accessible measure to probe quantum phase transitions, as it does not require preparing the equilibrium state.}, keywords = {}, pubstate = {published}, tppubtype = {article} } The experimental observation of quantum phase transitions predicted by the quantum Rabi model in quantum critical systems is usually challenging due to the lack of signature experimental observables associated with them. Here, we describe a method to identify the dynamical critical phenomenon in the quantum Rabi model consisting of a three-level atom and a cavity at the quantum phase transition. Such a critical phenomenon manifests itself as a sudden change of steady-state output photons in the system driven by two classical fields, when both the atom and the cavity are initially unexcited. The process occurs as the high-frequency pump field is converted into the low-frequency Stokes field and multiple cavity photons in the normal phase, while this conversion cannot occur in the superradiant phase. The sudden change of steady-state output photons is an experimentally accessible measure to probe quantum phase transitions, as it does not require preparing the equilibrium state. |
| 65. | Josef Kadlec, Karol Bartkiewicz, Antonín Černoch, Karel Lemr, Adam Miranowicz Opt. Express, 32 (2), pp. 2333–2346, 2024. @article{Kadlec:24, title = {Experimental hierarchy of the nonclassicality of single-qubit states via potentials for entanglement, steering, and Bell nonlocality}, author = {Josef Kadlec and Karol Bartkiewicz and Antonín Černoch and Karel Lemr and Adam Miranowicz}, url = {https://opg.optica.org/oe/abstract.cfm?URI=oe-32-2-2333}, doi = {10.1364/OE.506169}, year = {2024}, date = {2024-01-01}, journal = {Opt. Express}, volume = {32}, number = {2}, pages = {2333--2346}, publisher = {Optica Publishing Group}, abstract = {Entanglement potentials are a promising way to quantify the nonclassicality of single-mode states. They are defined by the amount of entanglement (expressed by, e.g., the Wootters concurrence) obtained after mixing the examined single-mode state with a purely classical state; such as the vacuum or a coherent state. We generalize the idea of entanglement potentials to other quantum correlations: the EPR steering and Bell nonlocality, thus enabling us to study mutual hierarchies of these nonclassicality potentials. Instead of the usual vacuum and one-photon superposition states, we experimentally test this concept using specially tailored polarization-encoded single-photon states. One polarization encodes a given nonclassical single-mode state, while the other serves as the vacuum place-holder. This technique proves to be experimentally more convenient in comparison to the vacuum and a one-photon superposition as it does not require the vacuum detection.}, keywords = {}, pubstate = {published}, tppubtype = {article} } Entanglement potentials are a promising way to quantify the nonclassicality of single-mode states. They are defined by the amount of entanglement (expressed by, e.g., the Wootters concurrence) obtained after mixing the examined single-mode state with a purely classical state; such as the vacuum or a coherent state. We generalize the idea of entanglement potentials to other quantum correlations: the EPR steering and Bell nonlocality, thus enabling us to study mutual hierarchies of these nonclassicality potentials. Instead of the usual vacuum and one-photon superposition states, we experimentally test this concept using specially tailored polarization-encoded single-photon states. One polarization encodes a given nonclassical single-mode state, while the other serves as the vacuum place-holder. This technique proves to be experimentally more convenient in comparison to the vacuum and a one-photon superposition as it does not require the vacuum detection. |
| 64. | Wei Qin, Anton Frisk Kockum, Carlos Sánchez Munoz, Adam Miranowicz, Franco Nori Quantum amplification and simulation of strong and ultrastrong coupling of light and matter Physics Reports, 1078 , pp. 1-59, 2024, ISSN: 0370-1573, (Quantum amplification and simulation of strong and ultrastrong coupling of light and matter). @article{Qin2024pr, title = {Quantum amplification and simulation of strong and ultrastrong coupling of light and matter}, author = {Wei Qin and Anton Frisk Kockum and Carlos Sánchez Munoz and Adam Miranowicz and Franco Nori}, url = {https://www.sciencedirect.com/science/article/pii/S0370157324001571}, doi = {https://doi.org/10.1016/j.physrep.2024.05.003}, issn = {0370-1573}, year = {2024}, date = {2024-01-01}, journal = {Physics Reports}, volume = {1078}, pages = {1-59}, abstract = {The interaction of light and matter at the single-photon level is of central importance in various fields of physics, including, e.g., condensed matter physics, astronomy, quantum optics, and quantum information. Amplification of such quantum lightmatter interaction can be highly beneficial to, e.g., improve device performance, explore novel phenomena, and understand fundamental physics, and has therefore been a long-standing goal. Furthermore, simulation of lightmatter interaction in the regime of ultrastrong coupling, where the interaction strength is comparable to the bare frequencies of the uncoupled systems, has also become a hot research topic, and considerable progress has been made both theoretically and experimentally in the past decade. In this review, we provide a detailed introduction of recent advances in amplification of quantum lightmatter interaction and simulation of ultrastrong lightmatter interaction, particularly in cavity and circuit quantum electrodynamics and in cavity optomechanics.}, note = {Quantum amplification and simulation of strong and ultrastrong coupling of light and matter}, keywords = {}, pubstate = {published}, tppubtype = {article} } The interaction of light and matter at the single-photon level is of central importance in various fields of physics, including, e.g., condensed matter physics, astronomy, quantum optics, and quantum information. Amplification of such quantum lightmatter interaction can be highly beneficial to, e.g., improve device performance, explore novel phenomena, and understand fundamental physics, and has therefore been a long-standing goal. Furthermore, simulation of lightmatter interaction in the regime of ultrastrong coupling, where the interaction strength is comparable to the bare frequencies of the uncoupled systems, has also become a hot research topic, and considerable progress has been made both theoretically and experimentally in the past decade. In this review, we provide a detailed introduction of recent advances in amplification of quantum lightmatter interaction and simulation of ultrastrong lightmatter interaction, particularly in cavity and circuit quantum electrodynamics and in cavity optomechanics. |
| 63. | Jan Roik, Karol Bartkiewicz, Antonín Černoch, Karel Lemr Routing in quantum communication networks using reinforcement machine learning Quantum Information Processing, 23 (3), 2024, ISSN: 1573-1332. @article{Roik2024, title = {Routing in quantum communication networks using reinforcement machine learning}, author = {Jan Roik and Karol Bartkiewicz and Antonín Černoch and Karel Lemr}, url = {http://dx.doi.org/10.1007/s11128-024-04287-z}, doi = {10.1007/s11128-024-04287-z}, issn = {1573-1332}, year = {2024}, date = {2024-01-01}, journal = {Quantum Information Processing}, volume = {23}, number = {3}, publisher = {Springer Science and Business Media LLC}, keywords = {}, pubstate = {published}, tppubtype = {article} } |
| 62. | Seungbeom Chin, Yong-Su Kim, Marcin Karczewski Shortcut to multipartite entanglement generation: A graph approach to boson subtractions npj Quantum Information, 10 (1), 2024, ISSN: 2056-6387. @article{Chin2024, title = {Shortcut to multipartite entanglement generation: A graph approach to boson subtractions}, author = {Seungbeom Chin and Yong-Su Kim and Marcin Karczewski}, url = {http://dx.doi.org/10.1038/s41534-024-00845-6}, doi = {10.1038/s41534-024-00845-6}, issn = {2056-6387}, year = {2024}, date = {2024-01-01}, journal = {npj Quantum Information}, volume = {10}, number = {1}, publisher = {Springer Science and Business Media LLC}, keywords = {}, pubstate = {published}, tppubtype = {article} } |
| 61. | Jolanta Natalia Latosińska, Magdalena Latosińska, Janez Seliger, Veselko Žagar, Tomaž Apih Pharmaceuticals, 17 (4), 2024, ISSN: 1424-8247. @article{ph17040445, title = {Butterfly Effect in Cytarabine: Combined NMR-NQR Experiment, Solid-State Computational Modeling, Quantitative Structure-Property Relationships and Molecular Docking Study}, author = {Jolanta Natalia Latosińska and Magdalena Latosińska and Janez Seliger and Veselko Žagar and Tomaž Apih}, url = {https://www.mdpi.com/1424-8247/17/4/445}, doi = {10.3390/ph17040445}, issn = {1424-8247}, year = {2024}, date = {2024-01-01}, journal = {Pharmaceuticals}, volume = {17}, number = {4}, abstract = {Cytarabine (Ara-C) is a synthetic isomer of cytidine that differs from cytidine and deoxycytidine only in the sugar. The use of arabinose instead of deoxyribose hinders the formation of phosphodiester linkages between pentoses, preventing the DNA chain from elongation and interrupting the DNA synthesis. The minor structural alteration (the inversion of hydroxyl at the 2′ positions of the sugar) leads to change of the biological activity from anti-depressant and DNA/RNA block builder to powerful anti-cancer. Our study aimed to determine the molecular nature of this phenomenon. Three 1H-14N NMR-NQR experimental techniques, followed by solid-state computational modelling (Quantum Theory of Atoms in Molecules, Reduced Density Gradient and 3D Hirshfeld surfaces), Quantitative Structure–Property Relationships, Spackman’s Hirshfeld surfaces and Molecular Docking were used. Multifaceted analysis—combining experiments, computational modeling and molecular docking—provides deep insight into three-dimensional packing at the atomic and molecular levels, but is challenging. A spectrum with nine lines indicating the existence of three chemically inequivalent nitrogen sites in the Ara-C molecule was recorded, and the lines were assigned to them. The influence of the structural alteration on the NQR parameters was modeled in the solid (GGA/RPBE). For the comprehensive description of the nature of these interactions several factors were considered, including relative reactivity and the involvement of heavy atoms in various non-covalent interactions. The binding modes in the solid state and complex with dCK were investigated using the novel approaches: radial plots, heatmaps and root-mean-square deviation of the binding mode. We identified the intramolecular OH···O hydrogen bond as the key factor responsible for forcing the glycone conformation and strengthening NH···O bonds with Gln97, Asp133 and Ara128, and stacking with Phe137. The titular butterfly effect is associated with both the inversion and the presence of this intramolecular hydrogen bond. Our study elucidates the differences in the binding modes of Ara-C and cytidine, which should guide the design of more potent anti-cancer and anti-viral analogues.}, keywords = {}, pubstate = {published}, tppubtype = {article} } Cytarabine (Ara-C) is a synthetic isomer of cytidine that differs from cytidine and deoxycytidine only in the sugar. The use of arabinose instead of deoxyribose hinders the formation of phosphodiester linkages between pentoses, preventing the DNA chain from elongation and interrupting the DNA synthesis. The minor structural alteration (the inversion of hydroxyl at the 2′ positions of the sugar) leads to change of the biological activity from anti-depressant and DNA/RNA block builder to powerful anti-cancer. Our study aimed to determine the molecular nature of this phenomenon. Three 1H-14N NMR-NQR experimental techniques, followed by solid-state computational modelling (Quantum Theory of Atoms in Molecules, Reduced Density Gradient and 3D Hirshfeld surfaces), Quantitative Structure–Property Relationships, Spackman’s Hirshfeld surfaces and Molecular Docking were used. Multifaceted analysis—combining experiments, computational modeling and molecular docking—provides deep insight into three-dimensional packing at the atomic and molecular levels, but is challenging. A spectrum with nine lines indicating the existence of three chemically inequivalent nitrogen sites in the Ara-C molecule was recorded, and the lines were assigned to them. The influence of the structural alteration on the NQR parameters was modeled in the solid (GGA/RPBE). For the comprehensive description of the nature of these interactions several factors were considered, including relative reactivity and the involvement of heavy atoms in various non-covalent interactions. The binding modes in the solid state and complex with dCK were investigated using the novel approaches: radial plots, heatmaps and root-mean-square deviation of the binding mode. We identified the intramolecular OH···O hydrogen bond as the key factor responsible for forcing the glycone conformation and strengthening NH···O bonds with Gln97, Asp133 and Ara128, and stacking with Phe137. The titular butterfly effect is associated with both the inversion and the presence of this intramolecular hydrogen bond. Our study elucidates the differences in the binding modes of Ara-C and cytidine, which should guide the design of more potent anti-cancer and anti-viral analogues. |
| 60. | Magdalena Latosińska, Jolanta Natalia Latosińska Molecules, 29 (2), pp. 441, 2024, ISSN: 1420-3049. @article{Latosiska2024, title = {Favipiravir Analogues as Inhibitors of SARS-CoV-2 RNA-Dependent RNA Polymerase, Combined Quantum Chemical Modeling, Quantitative Structure–Property Relationship, and Molecular Docking Study}, author = {Magdalena Latosińska and Jolanta Natalia Latosińska}, url = {http://dx.doi.org/10.3390/molecules29020441}, doi = {10.3390/molecules29020441}, issn = {1420-3049}, year = {2024}, date = {2024-01-01}, journal = {Molecules}, volume = {29}, number = {2}, pages = {441}, publisher = {MDPI AG}, keywords = {}, pubstate = {published}, tppubtype = {article} } |
| 59. | E S Hevorkian, V P Nerubatskyi, R V Vovk, T Szumiata, Jolanta Natalia Latosińska Foamy ceramic filters and new possibilities of their applications Ceramics International, 50 (4), pp. 6961–6968, 2024, ISSN: 0272-8842. @article{Hevorkian2024b, title = {Foamy ceramic filters and new possibilities of their applications}, author = {E S Hevorkian and V P Nerubatskyi and R V Vovk and T Szumiata and Jolanta Natalia Latosińska}, url = {http://dx.doi.org/10.1016/j.ceramint.2023.12.046}, doi = {10.1016/j.ceramint.2023.12.046}, issn = {0272-8842}, year = {2024}, date = {2024-01-01}, journal = {Ceramics International}, volume = {50}, number = {4}, pages = {6961–6968}, publisher = {Elsevier BV}, keywords = {}, pubstate = {published}, tppubtype = {article} } |
| 58. | Magdalena Latosińska, Jolanta Natalia Latosińska Molecules, 29 (13), 2024, ISSN: 1420-3049. @article{molecules29133199, title = {Serine/Threonine Protein Kinases as Attractive Targets for Anti-Cancer Drugs—An Innovative Approach to Ligand Tuning Using Combined Quantum Chemical Calculations, Molecular Docking, Molecular Dynamic Simulations, and Network-like Similarity Graphs}, author = {Magdalena Latosińska and Jolanta Natalia Latosińska}, url = {https://www.mdpi.com/1420-3049/29/13/3199}, doi = {10.3390/molecules29133199}, issn = {1420-3049}, year = {2024}, date = {2024-01-01}, journal = {Molecules}, volume = {29}, number = {13}, abstract = {Serine/threonine protein kinases (CK2, PIM-1, RIO1) are constitutively active, highly conserved, pleiotropic, and multifunctional kinases, which control several signaling pathways and regulate many cellular functions, such as cell activity, survival, proliferation, and apoptosis. Over the past decades, they have gained increasing attention as potential therapeutic targets, ranging from various cancers and neurological, inflammation, and autoimmune disorders to viral diseases, including COVID-19. Despite the accumulation of a vast amount of experimental data, there is still no “recipe” that would facilitate the search for new effective kinase inhibitors. The aim of our study was to develop an effective screening method that would be useful for this purpose. A combination of Density Functional Theory calculations and molecular docking, supplemented with newly developed quantitative methods for the comparison of the binding modes, provided deep insight into the set of desirable properties responsible for their inhibition. The mathematical metrics helped assess the distance between the binding modes, while heatmaps revealed the locations in the ligand that should be modified according to binding site requirements. The Structure-Binding Affinity Index and Structural-Binding Affinity Landscape proposed in this paper helped to measure the extent to which binding affinity is gained or lost in response to a relatively small change in the ligand’s structure. The combination of the physico-chemical profile with the aforementioned factors enabled the identification of both “dead” and “promising” search directions. Tests carried out on experimental data have validated and demonstrated the high efficiency of the proposed innovative approach. Our method for quantifying differences between the ligands and their binding capabilities holds promise for guiding future research on new anti-cancer agents.}, keywords = {}, pubstate = {published}, tppubtype = {article} } Serine/threonine protein kinases (CK2, PIM-1, RIO1) are constitutively active, highly conserved, pleiotropic, and multifunctional kinases, which control several signaling pathways and regulate many cellular functions, such as cell activity, survival, proliferation, and apoptosis. Over the past decades, they have gained increasing attention as potential therapeutic targets, ranging from various cancers and neurological, inflammation, and autoimmune disorders to viral diseases, including COVID-19. Despite the accumulation of a vast amount of experimental data, there is still no “recipe” that would facilitate the search for new effective kinase inhibitors. The aim of our study was to develop an effective screening method that would be useful for this purpose. A combination of Density Functional Theory calculations and molecular docking, supplemented with newly developed quantitative methods for the comparison of the binding modes, provided deep insight into the set of desirable properties responsible for their inhibition. The mathematical metrics helped assess the distance between the binding modes, while heatmaps revealed the locations in the ligand that should be modified according to binding site requirements. The Structure-Binding Affinity Index and Structural-Binding Affinity Landscape proposed in this paper helped to measure the extent to which binding affinity is gained or lost in response to a relatively small change in the ligand’s structure. The combination of the physico-chemical profile with the aforementioned factors enabled the identification of both “dead” and “promising” search directions. Tests carried out on experimental data have validated and demonstrated the high efficiency of the proposed innovative approach. Our method for quantifying differences between the ligands and their binding capabilities holds promise for guiding future research on new anti-cancer agents. |
| 57. | Edvin Hevorkian, Remigiusz Michalczewski, Miroslaw Rucki, Dmitry Sofronov, Edyta Osuch-Słomka, Volodymyr Nerubatskyi, Zbigniew Krzysiak, Jolanta Natalia Latosińska Ceramics International, 50 (19, Part A), pp. 35226-35235, 2024, ISSN: 0272-8842. @article{HEVORKIAN202435226, title = {Effect of the sintering parameters on the structure and mechanical properties of zirconia-based ceramics}, author = {Edvin Hevorkian and Remigiusz Michalczewski and Miroslaw Rucki and Dmitry Sofronov and Edyta Osuch-Słomka and Volodymyr Nerubatskyi and Zbigniew Krzysiak and Jolanta Natalia Latosińska}, url = {https://www.sciencedirect.com/science/article/pii/S0272884224027688}, doi = {https://doi.org/10.1016/j.ceramint.2024.06.331}, issn = {0272-8842}, year = {2024}, date = {2024-01-01}, journal = {Ceramics International}, volume = {50}, number = {19, Part A}, pages = {35226-35235}, abstract = {The paper presents the results of an investigations of the sintered zirconia ceramics that have been stabilized with Y2O3 and CeO2. The initial powders were synthesized via decomposition of the fluoride salts, which determined morphological features and dimensions of the particles. The specific electroconsolidation process, performed using the modified spark plasma sintering device, allowed for the retention of the nanoscale grain sizes and related properties of the sintered ceramic composites. It was found that the as-obtained materials with cerium oxide exhibited high bending strength of 609 MPa, by ca. 33 % higher than that of yttria-stabilized ones (410 MPa). In turn, the best combination of hardness and fracture toughness, K1С = 5.8 МPа·m1/2 аnd Нv = 14.8 GPа, respectively, exhibited ZrO2+3 wt% Y2O3. This result can be attributed to the chemical composition and morphology of the powders, which in turn is influenced by the synthesis conditions and calcination time and temperatures, as well as to the sintering parameters. In particular, yttria-stabilized zirconia showed higher sensitivity to the variations of the sintering temperatures and holding times.}, keywords = {}, pubstate = {published}, tppubtype = {article} } The paper presents the results of an investigations of the sintered zirconia ceramics that have been stabilized with Y2O3 and CeO2. The initial powders were synthesized via decomposition of the fluoride salts, which determined morphological features and dimensions of the particles. The specific electroconsolidation process, performed using the modified spark plasma sintering device, allowed for the retention of the nanoscale grain sizes and related properties of the sintered ceramic composites. It was found that the as-obtained materials with cerium oxide exhibited high bending strength of 609 MPa, by ca. 33 % higher than that of yttria-stabilized ones (410 MPa). In turn, the best combination of hardness and fracture toughness, K1С = 5.8 МPа·m1/2 аnd Нv = 14.8 GPа, respectively, exhibited ZrO2+3 wt% Y2O3. This result can be attributed to the chemical composition and morphology of the powders, which in turn is influenced by the synthesis conditions and calcination time and temperatures, as well as to the sintering parameters. In particular, yttria-stabilized zirconia showed higher sensitivity to the variations of the sintering temperatures and holding times. |
| 56. | Magdalena Latosińska, Jolanta Natalia Latosińska Viruses, 16 (7), 2024, ISSN: 1999-4915. @article{v16071073, title = {The Chameleon Strategy—A Recipe for Effective Ligand Screening for Viral Targets Based on Four Novel Structure–Binding Strength Indices}, author = {Magdalena Latosińska and Jolanta Natalia Latosińska}, url = {https://www.mdpi.com/1999-4915/16/7/1073}, doi = {10.3390/v16071073}, issn = {1999-4915}, year = {2024}, date = {2024-01-01}, journal = {Viruses}, volume = {16}, number = {7}, abstract = {The RNA viruses SARS-CoV, SARS-CoV-2 and MERS-CoV encode the non-structural Nsp16 (2′-O-methyltransferase) that catalyzes the transfer of a methyl group from S-adenosylmethionine (SAM) to the first ribonucleotide in mRNA. Recently, it has been found that breaking the bond between Nsp16 and SAM substrate results in the cessation of mRNA virus replication. To date, only a limited number of such inhibitors have been identified, which can be attributed to a lack of an effective “recipe”. The aim of our study was to propose and verify a rapid and effective screening protocol dedicated to such purposes. We proposed four new indices describing structure-binding strength (structure–binding affinity, structure–hydrogen bonding, structure–steric and structure–protein–ligand indices) were then applied and shown to be extremely helpful in determining the degree of increase or decrease in binding affinity in response to a relatively small change in the ligand structure. After initial pre-selection, based on similarity to SAM, we limited the study to 967 compounds, so-called molecular chameleons. They were then docked in the Nsp16 protein pocket, and 10 candidate ligands were selected using the novel structure-binding affinity index. Subsequently the selected 10 candidate ligands and 8 known inhibitors and were docked to Nsp16 pockets from SARS-CoV-2, MERS-CoV and SARS-CoV. Based on the four new indices, the best ligands were selected and a new one was designed by tuning them. Finally, ADMET profiling and molecular dynamics simulations were performed for the best ligands. The new structure-binding strength indices can be successfully applied not only to screen and tune ligands, but also to determine the effectiveness of the ligand in response to changes in the target viral entity, which is particularly useful for assessing drug effectiveness in the case of alterations in viral proteins. The developed approach, the so-called chameleon strategy, has the capacity to introduce a novel universal paradigm to the field of drugs design, including RNA antivirals.}, keywords = {}, pubstate = {published}, tppubtype = {article} } The RNA viruses SARS-CoV, SARS-CoV-2 and MERS-CoV encode the non-structural Nsp16 (2′-O-methyltransferase) that catalyzes the transfer of a methyl group from S-adenosylmethionine (SAM) to the first ribonucleotide in mRNA. Recently, it has been found that breaking the bond between Nsp16 and SAM substrate results in the cessation of mRNA virus replication. To date, only a limited number of such inhibitors have been identified, which can be attributed to a lack of an effective “recipe”. The aim of our study was to propose and verify a rapid and effective screening protocol dedicated to such purposes. We proposed four new indices describing structure-binding strength (structure–binding affinity, structure–hydrogen bonding, structure–steric and structure–protein–ligand indices) were then applied and shown to be extremely helpful in determining the degree of increase or decrease in binding affinity in response to a relatively small change in the ligand structure. After initial pre-selection, based on similarity to SAM, we limited the study to 967 compounds, so-called molecular chameleons. They were then docked in the Nsp16 protein pocket, and 10 candidate ligands were selected using the novel structure-binding affinity index. Subsequently the selected 10 candidate ligands and 8 known inhibitors and were docked to Nsp16 pockets from SARS-CoV-2, MERS-CoV and SARS-CoV. Based on the four new indices, the best ligands were selected and a new one was designed by tuning them. Finally, ADMET profiling and molecular dynamics simulations were performed for the best ligands. The new structure-binding strength indices can be successfully applied not only to screen and tune ligands, but also to determine the effectiveness of the ligand in response to changes in the target viral entity, which is particularly useful for assessing drug effectiveness in the case of alterations in viral proteins. The developed approach, the so-called chameleon strategy, has the capacity to introduce a novel universal paradigm to the field of drugs design, including RNA antivirals. |
| 55. | Jan Wójcik Quantum walks in weak stochastic gauge fields Physics Letters A, 512 , pp. 129605, 2024, ISSN: 0375-9601. @article{WOJCIK2024129605, title = {Quantum walks in weak stochastic gauge fields}, author = {Jan Wójcik}, url = {https://www.sciencedirect.com/science/article/pii/S0375960124002998}, doi = {https://doi.org/10.1016/j.physleta.2024.129605}, issn = {0375-9601}, year = {2024}, date = {2024-01-01}, journal = {Physics Letters A}, volume = {512}, pages = {129605}, abstract = {Contrary to the ballistic dynamics of standard quantum walks, the behavior of stochastic quantum walks is known to be diffusive. Here we study discrete time quantum walks in weak stochastic gauge fields. In the case of position and spin dependent gauge field, we observe a transition from ballistic to diffusive motion, with the probability distribution becoming Gaussian. However, in contradiction to common belief, weak stochastic electric gauge fields reveal the persistence of Bloch oscillations despite decoherence which we demonstrate on simulations and prove analytically. The proposed models provide insights into the interplay between randomness and coherent dynamics of quantum walks.}, keywords = {}, pubstate = {published}, tppubtype = {article} } Contrary to the ballistic dynamics of standard quantum walks, the behavior of stochastic quantum walks is known to be diffusive. Here we study discrete time quantum walks in weak stochastic gauge fields. In the case of position and spin dependent gauge field, we observe a transition from ballistic to diffusive motion, with the probability distribution becoming Gaussian. However, in contradiction to common belief, weak stochastic electric gauge fields reveal the persistence of Bloch oscillations despite decoherence which we demonstrate on simulations and prove analytically. The proposed models provide insights into the interplay between randomness and coherent dynamics of quantum walks. |
2023 |
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| 54. | Andrzej Grudka, Paweł Kurzyński, Adam S Sajna, Jan Wójcik, Antoni Wójcik Exposing hypersensitivity in quantum chaotic dynamics Phys. Rev. E, 108 , pp. 064212, 2023. @article{PhysRevE.108.064212, title = {Exposing hypersensitivity in quantum chaotic dynamics}, author = {Andrzej Grudka and Paweł Kurzyński and Adam S Sajna and Jan Wójcik and Antoni Wójcik}, url = {https://link.aps.org/doi/10.1103/PhysRevE.108.064212}, doi = {10.1103/PhysRevE.108.064212}, year = {2023}, date = {2023-12-01}, journal = {Phys. Rev. E}, volume = {108}, pages = {064212}, publisher = {American Physical Society}, keywords = {}, pubstate = {published}, tppubtype = {article} } |
| 53. | Javid Naikoo, Ravindra W. Chhajlany, Jan Kołodyński Multiparameter Estimation Perspective on Non-Hermitian Singularity-Enhanced Sensing Phys. Rev. Lett., 131 , pp. 220801, 2023. @article{PhysRevLett.131.220801, title = {Multiparameter Estimation Perspective on Non-Hermitian Singularity-Enhanced Sensing}, author = {Javid Naikoo and Ravindra W. Chhajlany and Jan Kołodyński}, url = {https://link.aps.org/doi/10.1103/PhysRevLett.131.220801}, doi = {10.1103/PhysRevLett.131.220801}, year = {2023}, date = {2023-11-29}, journal = {Phys. Rev. Lett.}, volume = {131}, pages = {220801}, publisher = {American Physical Society}, abstract = {Describing the evolution of quantum systems by means of non-Hermitian generators opens a new avenue to explore the dynamical properties naturally emerging in such a picture, e.g. operation at the so-called exceptional points, preservation of parity-time symmetry, or capitalizing on the singular behavior of the dynamics. In this Letter, we focus on the possibility of achieving unbounded sensitivity when using the system to sense linear perturbations away from a singular point. By combining multiparameter estimation theory of Gaussian quantum systems with the one of singular-matrix perturbations, we introduce the necessary tools to study the ultimate limits on the precision attained by such singularity-tuned sensors. We identify under what conditions and at what rate can the resulting sensitivity indeed diverge, in order to show that nuisance parameters should be generally included in the analysis, as their presence may alter the scaling of the error with the estimated parameter.}, keywords = {}, pubstate = {published}, tppubtype = {article} } Describing the evolution of quantum systems by means of non-Hermitian generators opens a new avenue to explore the dynamical properties naturally emerging in such a picture, e.g. operation at the so-called exceptional points, preservation of parity-time symmetry, or capitalizing on the singular behavior of the dynamics. In this Letter, we focus on the possibility of achieving unbounded sensitivity when using the system to sense linear perturbations away from a singular point. By combining multiparameter estimation theory of Gaussian quantum systems with the one of singular-matrix perturbations, we introduce the necessary tools to study the ultimate limits on the precision attained by such singularity-tuned sensors. We identify under what conditions and at what rate can the resulting sensitivity indeed diverge, in order to show that nuisance parameters should be generally included in the analysis, as their presence may alter the scaling of the error with the estimated parameter. |
| 52. | Andrzej Grudka, Jȩdrzej Stempin, Jan Wójcik, Antoni Wójcik Superluminal observers do not explain quantum superpositions Physics Letters A, 487 , pp. 129127, 2023. @article{Grudka2023, title = {Superluminal observers do not explain quantum superpositions}, author = {Andrzej Grudka and Jȩdrzej Stempin and Jan Wójcik and Antoni Wójcik}, url = {https://www.sciencedirect.com/science/article/pii/S0375960123005078}, doi = {10.1016/j.physleta.2023.129127}, year = {2023}, date = {2023-11-05}, journal = {Physics Letters A}, volume = {487}, pages = {129127}, abstract = {The quantum description of reality is quite different from the classical one. Understanding this difference at a fundamental level is still an interesting topic. Recently, Dragan and Ekert (2020) postulated that considering so-called superluminal observers can be useful in this context. In particular, they claim that the full mathematical structure of the generalized Lorentz transformation may imply the emergence of multiple quantum mechanical trajectories. On the contrary, here we show that the generalized Lorentz transformation, when used in a consistent way, does not provide any correspondence between the classical concept of a definite path and the multiple paths of quantum mechanics.}, keywords = {}, pubstate = {published}, tppubtype = {article} } The quantum description of reality is quite different from the classical one. Understanding this difference at a fundamental level is still an interesting topic. Recently, Dragan and Ekert (2020) postulated that considering so-called superluminal observers can be useful in this context. In particular, they claim that the full mathematical structure of the generalized Lorentz transformation may imply the emergence of multiple quantum mechanical trajectories. On the contrary, here we show that the generalized Lorentz transformation, when used in a consistent way, does not provide any correspondence between the classical concept of a definite path and the multiple paths of quantum mechanics. |
| 51. | Ievgen I. Arkhipov, Adam Miranowicz, Franco Nori, Şahin K. Özdemir, Fabrizio Minganti Fully solvable finite simplex lattices with open boundaries in arbitrary dimensions Phys. Rev. Res., 5 , pp. 043092, 2023. @article{Arkhipov2023b, title = {Fully solvable finite simplex lattices with open boundaries in arbitrary dimensions}, author = {Ievgen I. Arkhipov and Adam Miranowicz and Franco Nori and Şahin K. Özdemir and Fabrizio Minganti}, url = {https://link.aps.org/doi/10.1103/PhysRevResearch.5.043092}, doi = {10.1103/PhysRevResearch.5.043092}, year = {2023}, date = {2023-10-26}, journal = {Phys. Rev. Res.}, volume = {5}, pages = {043092}, abstract = {Finite simplex lattice models are used in different branches of science, e.g., in condensed-matter physics, when studying frustrated magnetic systems and non-Hermitian localization phenomena; or in chemistry, when describing experiments with mixtures. An n-simplex represents the simplest possible polytope in n dimensions, e.g., a line segment, a triangle, and a tetrahedron in one, two, and three dimensions, respectively. In this work, we show that various fully solvable, in general non-Hermitian, n-simplex lattice models with open boundaries can be constructed from the high-order field-moments space of quadratic bosonic systems. Namely, we demonstrate that such n-simplex lattices can be formed by a dimensional reduction of highly degenerate iterated polytope chains in (k>n)-dimensions, which naturally emerge in the field-moments space. Our findings indicate that the field-moments space of bosonic systems provides a versatile platform for simulating real-space n-simplex lattices exhibiting non-Hermitian phenomena, and it yields valuable insights into the structure of many-body systems exhibiting similar complexity. Among a variety of practical applications, these simplex structures can offer a physical setting for implementing the discrete fractional Fourier transform, an indispensable tool for both quantum and classical signal processing.}, keywords = {}, pubstate = {published}, tppubtype = {article} } Finite simplex lattice models are used in different branches of science, e.g., in condensed-matter physics, when studying frustrated magnetic systems and non-Hermitian localization phenomena; or in chemistry, when describing experiments with mixtures. An n-simplex represents the simplest possible polytope in n dimensions, e.g., a line segment, a triangle, and a tetrahedron in one, two, and three dimensions, respectively. In this work, we show that various fully solvable, in general non-Hermitian, n-simplex lattice models with open boundaries can be constructed from the high-order field-moments space of quadratic bosonic systems. Namely, we demonstrate that such n-simplex lattices can be formed by a dimensional reduction of highly degenerate iterated polytope chains in (k>n)-dimensions, which naturally emerge in the field-moments space. Our findings indicate that the field-moments space of bosonic systems provides a versatile platform for simulating real-space n-simplex lattices exhibiting non-Hermitian phenomena, and it yields valuable insights into the structure of many-body systems exhibiting similar complexity. Among a variety of practical applications, these simplex structures can offer a physical setting for implementing the discrete fractional Fourier transform, an indispensable tool for both quantum and classical signal processing. |
| 50. | Jan Peřina, Jr., Adam Miranowicz, Joanna K. Kalaga, Wiesław Leoński Unavoidability of nonclassicality loss in PT-symmetric systems Phys. Rev. A, 108 , pp. 033512, 2023. @article{Peřina2023, title = {Unavoidability of nonclassicality loss in PT-symmetric systems}, author = {Jan Peřina, Jr. and Adam Miranowicz and Joanna K. Kalaga and Wiesław Leoński}, url = {https://journals.aps.org/pra/abstract/10.1103/PhysRevA.108.033512}, doi = {10.1103/PhysRevA.108.033512}, year = {2023}, date = {2023-09-15}, journal = {Phys. Rev. A}, volume = {108}, pages = {033512}, abstract = {We show that the loss of nonclassicality (including quantum entanglement) cannot be compensated by the (incoherent) amplification of PT-symmetric systems. We address this problem by manipulating the quantum fluctuating forces in the Heisenberg-Langevin approach. Specifically, we analyze the dynamics of two nonlinearly coupled oscillator modes in a PT-symmetric system. An analytical solution allows us to separate the contribution of reservoir fluctuations from the evolution of quantum statistical properties of the modes. In general, as reservoir fluctuations act constantly, the complete loss of nonclassicality and entanglement is observed for long times. To elucidate the role of reservoir fluctuations in a long-time evolution of nonclassicality and entanglement, we consider and compare the predictions from two alternative models in which no fatal long-time detrimental effects on the nonclassicality and entanglement are observed. This is so as, in the first semiclassical model, no reservoir fluctuations are considered at all. This, however, violates the fluctuation-dissipation theorem. The second, more elaborated, model obeys the fluctuation-dissipation relations as it partly involves reservoir fluctuations. However, to prevent the above long-time detrimental effects, the reservoir fluctuations have to be endowed with the nonphysical properties of a sink model. In both models, additional incorporation of the omitted reservoir fluctuations results in their physically consistent behavior. This behavior, however, predicts the gradual loss of the nonclassicality and entanglement. Thus the effects of reservoir fluctuations related to damping cannot be compensated by those related to amplification. This qualitatively differs from the influence of damping and amplification to a direct coherent dynamics of PT-symmetric systems in which their mutual interference results in a periodic behavior allowing for nonclassicality and entanglement at arbitrary times.}, keywords = {}, pubstate = {published}, tppubtype = {article} } We show that the loss of nonclassicality (including quantum entanglement) cannot be compensated by the (incoherent) amplification of PT-symmetric systems. We address this problem by manipulating the quantum fluctuating forces in the Heisenberg-Langevin approach. Specifically, we analyze the dynamics of two nonlinearly coupled oscillator modes in a PT-symmetric system. An analytical solution allows us to separate the contribution of reservoir fluctuations from the evolution of quantum statistical properties of the modes. In general, as reservoir fluctuations act constantly, the complete loss of nonclassicality and entanglement is observed for long times. To elucidate the role of reservoir fluctuations in a long-time evolution of nonclassicality and entanglement, we consider and compare the predictions from two alternative models in which no fatal long-time detrimental effects on the nonclassicality and entanglement are observed. This is so as, in the first semiclassical model, no reservoir fluctuations are considered at all. This, however, violates the fluctuation-dissipation theorem. The second, more elaborated, model obeys the fluctuation-dissipation relations as it partly involves reservoir fluctuations. However, to prevent the above long-time detrimental effects, the reservoir fluctuations have to be endowed with the nonphysical properties of a sink model. In both models, additional incorporation of the omitted reservoir fluctuations results in their physically consistent behavior. This behavior, however, predicts the gradual loss of the nonclassicality and entanglement. Thus the effects of reservoir fluctuations related to damping cannot be compensated by those related to amplification. This qualitatively differs from the influence of damping and amplification to a direct coherent dynamics of PT-symmetric systems in which their mutual interference results in a periodic behavior allowing for nonclassicality and entanglement at arbitrary times. |
| 49. | Jolanta Natalia Latosińska, Magdalena Latosińska, Janez Seliger, Veselko Žagar Processes, 11 (9), 2023, ISSN: 2227-9717. @article{pr11092740, title = {Exploring Partial Structural Disorder in Anhydrous Paraxanthine through Combined Experiment, Solid-State Computational Modelling, and Molecular Docking}, author = {Jolanta Natalia Latosińska and Magdalena Latosińska and Janez Seliger and Veselko Žagar}, url = {https://www.mdpi.com/2227-9717/11/9/2740}, doi = {10.3390/pr11092740}, issn = {2227-9717}, year = {2023}, date = {2023-09-14}, journal = {Processes}, volume = {11}, number = {9}, abstract = {Paraxanthine (PX), a major metabolite of caffeine, a protective agent against Alzheimer’s and Parkinson’s disease, and a promising drug for the treatment of post-COVID 2019 anosmia and ageusia, has been studied in the solid state and protein–ligand complex. Partial disorder in PX, caused by the methyl group at the N(7) position, has been modelled and discussed. The relationship between the unusual structural disorder and the propensity to form a specific system of non-covalent bonds was analyzed. Three 1H-14N NMR-NQR (nuclear magnetic resonance–nuclear quadrupole resonance) experimental techniques were used, namely multiple frequency sweeps, Larmor frequency scanning, and the two-frequency irradiation, followed by solid-state computational modelling (density functional theory, supplemented by quantum theory of atoms in molecules, 3D Hirshfeld surfaces, and reduced density gradient), and molecular docking approaches. New quantitative methods for estimating changes in the global pattern of interactions under the influence of rotation of the methyl group in N(7) based on the Pompeiu–Hausdorff and Bhattacharayya metrics and the Wasserstein distance have been proposed and applied. A spectrum consisting of 12 lines, indicating the presence of 4 chemically inequivalent nitrogen sites in the PX molecule, was recorded, and the lines’ assignment to particular sites was made. The influence of the methyl rotation on the eigenvalues and eigenvectors of the electric field gradient tensor, NQR parameters, and resonance line positions was modelled in the solid (GGA/RPBE, m-GGA/RSCAN) and cluster (Minnesota M062X hybrid). Three factors have been found to determine structural disorder in PX: larger crystal voids near the methyl at N(7) than at N(1) (opening the path for the disorder), hyperconjugation strongly affecting the density distribution in the five-membered ring, and the involvement of the methyl group at N(7) in many non-covalent bonds that intercept (capture) subsequent jumping protons. The Pompeiu–Hausdorff and Bhattacharayya metrics and the Wasserstein distance confirmed the changes in the distribution and strength of non-covalent interactions throughout the molecule as a result of methyl rotation. This effect is clearly visible regardless of the type of metric, and its order of magnitude is consistent with the modulation effect of the NQR spectra (experimental and calculated). Through molecular docking, it was discovered that the PX moiety in protein–ligand complexes adopt the same methyl group conformation at N(7) as in the solid state. It was found that the cooperation–competition between the C-H⋯O hydrogen bonds and C-H⋯H-C dispersion interactions is the crucial factor that impedes methyl rotation and induces structural disorder, as well as being an important factor in the formation of the protein–ligand complexes.}, keywords = {}, pubstate = {published}, tppubtype = {article} } Paraxanthine (PX), a major metabolite of caffeine, a protective agent against Alzheimer’s and Parkinson’s disease, and a promising drug for the treatment of post-COVID 2019 anosmia and ageusia, has been studied in the solid state and protein–ligand complex. Partial disorder in PX, caused by the methyl group at the N(7) position, has been modelled and discussed. The relationship between the unusual structural disorder and the propensity to form a specific system of non-covalent bonds was analyzed. Three 1H-14N NMR-NQR (nuclear magnetic resonance–nuclear quadrupole resonance) experimental techniques were used, namely multiple frequency sweeps, Larmor frequency scanning, and the two-frequency irradiation, followed by solid-state computational modelling (density functional theory, supplemented by quantum theory of atoms in molecules, 3D Hirshfeld surfaces, and reduced density gradient), and molecular docking approaches. New quantitative methods for estimating changes in the global pattern of interactions under the influence of rotation of the methyl group in N(7) based on the Pompeiu–Hausdorff and Bhattacharayya metrics and the Wasserstein distance have been proposed and applied. A spectrum consisting of 12 lines, indicating the presence of 4 chemically inequivalent nitrogen sites in the PX molecule, was recorded, and the lines’ assignment to particular sites was made. The influence of the methyl rotation on the eigenvalues and eigenvectors of the electric field gradient tensor, NQR parameters, and resonance line positions was modelled in the solid (GGA/RPBE, m-GGA/RSCAN) and cluster (Minnesota M062X hybrid). Three factors have been found to determine structural disorder in PX: larger crystal voids near the methyl at N(7) than at N(1) (opening the path for the disorder), hyperconjugation strongly affecting the density distribution in the five-membered ring, and the involvement of the methyl group at N(7) in many non-covalent bonds that intercept (capture) subsequent jumping protons. The Pompeiu–Hausdorff and Bhattacharayya metrics and the Wasserstein distance confirmed the changes in the distribution and strength of non-covalent interactions throughout the molecule as a result of methyl rotation. This effect is clearly visible regardless of the type of metric, and its order of magnitude is consistent with the modulation effect of the NQR spectra (experimental and calculated). Through molecular docking, it was discovered that the PX moiety in protein–ligand complexes adopt the same methyl group conformation at N(7) as in the solid state. It was found that the cooperation–competition between the C-H⋯O hydrogen bonds and C-H⋯H-C dispersion interactions is the crucial factor that impedes methyl rotation and induces structural disorder, as well as being an important factor in the formation of the protein–ligand complexes. |
| 48. | Ri-Hua Zheng, Wen Ning, Ye-Hong Chen, Jia-Hao Lü, Li-Tuo Shen, Kai Xu, Yu-Ran Zhang, Da Xu, Hekang Li, Yan Xia, Fan Wu, Zhen-Biao Yang, Adam Miranowicz, Neill Lambert, Dongning Zheng, Heng Fan, Franco Nori, Shi-Biao Zheng Observation of a Superradiant Phase Transition with Emergent Cat States Phys. Rev. Lett., 131 , pp. 113601 , 2023. @article{Zheng2023, title = {Observation of a Superradiant Phase Transition with Emergent Cat States}, author = {Ri-Hua Zheng and Wen Ning and Ye-Hong Chen and Jia-Hao Lü and Li-Tuo Shen and Kai Xu and Yu-Ran Zhang and Da Xu and Hekang Li and Yan Xia and Fan Wu and Zhen-Biao Yang and Adam Miranowicz and Neill Lambert and Dongning Zheng and Heng Fan and Franco Nori and Shi-Biao Zheng}, url = {https://journals.aps.org/prl/abstract/10.1103/PhysRevLett.131.113601}, doi = {10.1103/PhysRevLett.131.113601}, year = {2023}, date = {2023-09-11}, journal = {Phys. Rev. Lett.}, volume = {131}, pages = {113601 }, abstract = {Superradiant phase transitions (SPTs) are important for understanding light-matter interactions at the quantum level, and play a central role in criticality-enhanced quantum sensing. So far, SPTs have been observed in driven-dissipative systems, but the emergent light fields did not show any nonclassical characteristic due to the presence of strong dissipation. Here we report an experimental demonstration of the SPT featuring the emergence of a highly nonclassical photonic field, realized with a resonator coupled to a superconducting qubit, implementing the quantum Rabi model. We fully characterize the light-matter state by Wigner matrix tomography. The measured matrix elements exhibit quantum interference intrinsic of a photonic mesoscopic superposition, and reveal light-matter entanglement.}, keywords = {}, pubstate = {published}, tppubtype = {article} } Superradiant phase transitions (SPTs) are important for understanding light-matter interactions at the quantum level, and play a central role in criticality-enhanced quantum sensing. So far, SPTs have been observed in driven-dissipative systems, but the emergent light fields did not show any nonclassical characteristic due to the presence of strong dissipation. Here we report an experimental demonstration of the SPT featuring the emergence of a highly nonclassical photonic field, realized with a resonator coupled to a superconducting qubit, implementing the quantum Rabi model. We fully characterize the light-matter state by Wigner matrix tomography. The measured matrix elements exhibit quantum interference intrinsic of a photonic mesoscopic superposition, and reveal light-matter entanglement. |
| 47. | Karol Bartkiewicz, Patrycja Tulewicz, Jan Roik, Karel Lemr Synergic quantum generative machine learning Scientific Reports, 13 (1), pp. 12893, 2023, ISSN: 2045-2322. @article{bartkiewicz_synergic_2023, title = {Synergic quantum generative machine learning}, author = {Karol Bartkiewicz and Patrycja Tulewicz and Jan Roik and Karel Lemr}, url = {https://www.nature.com/articles/s41598-023-40137-1}, doi = {10.1038/s41598-023-40137-1}, issn = {2045-2322}, year = {2023}, date = {2023-08-09}, urldate = {2023-10-18}, journal = {Scientific Reports}, volume = {13}, number = {1}, pages = {12893}, abstract = {We introduce a new approach towards generative quantum machine learning significantly reducing the number of hyperparameters and report on a proof-of-principle experiment demonstrating our approach. Our proposal depends on collaboration between the generators and discriminator, thus, we call it quantum synergic generative learning. We present numerical evidence that the synergic approach, in some cases, compares favorably to recently proposed quantum generative adversarial learning. In addition to the results obtained with quantum simulators, we also present experimental results obtained with an actual programmable quantum computer. We investigate how a quantum computer implementing generative learning algorithm could learn the concept of a maximally-entangled state. After completing the learning process, the network is able both to recognize and to generate an entangled state. Our approach can be treated as one possible preliminary step to understanding how the concept of quantum entanglement can be learned and demonstrated by a quantum computer.}, keywords = {}, pubstate = {published}, tppubtype = {article} } We introduce a new approach towards generative quantum machine learning significantly reducing the number of hyperparameters and report on a proof-of-principle experiment demonstrating our approach. Our proposal depends on collaboration between the generators and discriminator, thus, we call it quantum synergic generative learning. We present numerical evidence that the synergic approach, in some cases, compares favorably to recently proposed quantum generative adversarial learning. In addition to the results obtained with quantum simulators, we also present experimental results obtained with an actual programmable quantum computer. We investigate how a quantum computer implementing generative learning algorithm could learn the concept of a maximally-entangled state. After completing the learning process, the network is able both to recognize and to generate an entangled state. Our approach can be treated as one possible preliminary step to understanding how the concept of quantum entanglement can be learned and demonstrated by a quantum computer. |
| 46. | Andrzej Grudka, Paweł Kurzyński, Tomasz P Polak, Adam S Sajna, Jan Wójcik, Antoni Wójcik Complementarity in quantum walks Journal of Physics A, 56 , pp. 275303, 2023. @article{grudka23-2, title = {Complementarity in quantum walks}, author = {Andrzej Grudka and Paweł Kurzyński and Tomasz P Polak and Adam S Sajna and Jan Wójcik and Antoni Wójcik}, doi = {10.1088/1751-8121/acdcd0}, year = {2023}, date = {2023-06-19}, journal = {Journal of Physics A}, volume = {56}, pages = {275303}, abstract = {The eigenbases of two quantum observables, {|ai⟩}Di=1 and {|bj⟩}Dj=1, form mutually unbiased bases (MUB) if |⟨ai |bj⟩| = 1/ √D for all i and j. In realistic situations MUB are hard to obtain and one looks for approximate MUB (AMUB), in which case the corresponding eigenbases obey |⟨ai |bj⟩| ⩽ c/√D, where c is some positive constant independent of D. In majority of cases observables corresponding to MUB and AMUB do not have clear physical interpretation. Here we study discrete-time quantum walks (QWs) on d-cycles with a position and coin-dependent phase-shift. Such a model simulates a dynamics of a quantum particle moving on a ring with an artificial gauge field. In our case the amplitude of the phase-shift is governed by a single discrete parameter q. We solve the model analytically and observe that for prime d the eigenvectors of two QW evolution operators form AMUB. Namely, if d is prime the corresponding eigenvectors of the evolution operators, that act in the D-dimensional Hilbert space (D = 2d), obey |⟨vq|v ′q ′ ⟩| ⩽√2/√D for q ̸= q ′ and for all |vq⟩ and |v ′q ′ ⟩. Finally, we show that the analogous AMUB relation still holds in the continuous version of this model, which corresponds to a one-dimensional Dirac particle.}, keywords = {}, pubstate = {published}, tppubtype = {article} } The eigenbases of two quantum observables, {|ai⟩}Di=1 and {|bj⟩}Dj=1, form mutually unbiased bases (MUB) if |⟨ai |bj⟩| = 1/ √D for all i and j. In realistic situations MUB are hard to obtain and one looks for approximate MUB (AMUB), in which case the corresponding eigenbases obey |⟨ai |bj⟩| ⩽ c/√D, where c is some positive constant independent of D. In majority of cases observables corresponding to MUB and AMUB do not have clear physical interpretation. Here we study discrete-time quantum walks (QWs) on d-cycles with a position and coin-dependent phase-shift. Such a model simulates a dynamics of a quantum particle moving on a ring with an artificial gauge field. In our case the amplitude of the phase-shift is governed by a single discrete parameter q. We solve the model analytically and observe that for prime d the eigenvectors of two QW evolution operators form AMUB. Namely, if d is prime the corresponding eigenvectors of the evolution operators, that act in the D-dimensional Hilbert space (D = 2d), obey |⟨vq|v ′q ′ ⟩| ⩽√2/√D for q ̸= q ′ and for all |vq⟩ and |v ′q ′ ⟩. Finally, we show that the analogous AMUB relation still holds in the continuous version of this model, which corresponds to a one-dimensional Dirac particle. |
| 45. | Shilan Abo, Jan Soubusta, Kateřina Jiráková, Karol Bartkiewicz, Antonín Černoch, Karel Lemr, Adam Miranowicz Experimental hierarchy of two-qubit quantum correlations without state tomography Scientific Reports, 13 (1), pp. 8564, 2023, ISSN: 2045-2322. @article{abo_experimental_2023, title = {Experimental hierarchy of two-qubit quantum correlations without state tomography}, author = {Shilan Abo and Jan Soubusta and Kateřina Jiráková and Karol Bartkiewicz and Antonín Černoch and Karel Lemr and Adam Miranowicz}, url = {https://www.nature.com/articles/s41598-023-35015-9}, doi = {10.1038/s41598-023-35015-9}, issn = {2045-2322}, year = {2023}, date = {2023-05-26}, urldate = {2023-10-18}, journal = {Scientific Reports}, volume = {13}, number = {1}, pages = {8564}, abstract = {A Werner state, which is the singlet Bell state affected by white noise, is a prototype example of states, which can reveal a hierarchy of quantum entanglement, steering, and Bell nonlocality by controlling the amount of noise. However, experimental demonstrations of this hierarchy in a sufficient and necessary way (i.e., by applying measures or universal witnesses of these quantum correlations) have been mainly based on full quantum state tomography, corresponding to measuring at least 15 real parameters of two-qubit states. Here we report an experimental demonstration of this hierarchy by measuring only six elements of a correlation matrix depending on linear combinations of two-qubit Stokes parameters. We show that our experimental setup can also reveal the hierarchy of these quantum correlations of generalized Werner states, which are any two-qubit pure states affected by white noise.}, keywords = {}, pubstate = {published}, tppubtype = {article} } A Werner state, which is the singlet Bell state affected by white noise, is a prototype example of states, which can reveal a hierarchy of quantum entanglement, steering, and Bell nonlocality by controlling the amount of noise. However, experimental demonstrations of this hierarchy in a sufficient and necessary way (i.e., by applying measures or universal witnesses of these quantum correlations) have been mainly based on full quantum state tomography, corresponding to measuring at least 15 real parameters of two-qubit states. Here we report an experimental demonstration of this hierarchy by measuring only six elements of a correlation matrix depending on linear combinations of two-qubit Stokes parameters. We show that our experimental setup can also reveal the hierarchy of these quantum correlations of generalized Werner states, which are any two-qubit pure states affected by white noise. |
| 44. | Ievgen I. Arkhipov, Adam Miranowicz, Fabrizio Minganti, Şahin K. Özdemir, Franco Nori Nature Communications, 14 (2076), 2023. @article{Arkhipov2023, title = {Dynamically crossing diabolic points while encircling exceptional curves: A programmable symmetric-asymmetric multimode switch}, author = {Ievgen I. Arkhipov and Adam Miranowicz and Fabrizio Minganti and Şahin K. Özdemir and Franco Nori}, url = {https://www.nature.com/articles/s41467-023-37275-5}, doi = {doi.org/10.1038/s41467-023-37275-5}, year = {2023}, date = {2023-04-12}, journal = {Nature Communications}, volume = {14}, number = {2076}, abstract = {Nontrivial spectral properties of non-Hermitian systems can lead to intriguing effects with no counterparts in Hermitian systems. For instance, in a two-mode photonic system, by dynamically winding around an exceptional point (EP) a controlled asymmetric-symmetric mode switching can be realized. That is, the system can either end up in one of its eigenstates, regardless of the initial eigenmode, or it can switch between the two states on demand, by simply controlling the winding direction. However, for multimode systems with higher-order EPs or multiple low-order EPs, the situation can be more involved, and the ability to control asymmetric-symmetric mode switching can be impeded, due to the breakdown of adiabaticity. Here we demonstrate that this difficulty can be overcome by winding around exceptional curves by additionally crossing diabolic points. We consider a four-mode PT-symmetric bosonic system as a platform for experimental realization of such a multimode switch. Our work provides alternative routes for light manipulations in non-Hermitian photonic setups.}, keywords = {}, pubstate = {published}, tppubtype = {article} } Nontrivial spectral properties of non-Hermitian systems can lead to intriguing effects with no counterparts in Hermitian systems. For instance, in a two-mode photonic system, by dynamically winding around an exceptional point (EP) a controlled asymmetric-symmetric mode switching can be realized. That is, the system can either end up in one of its eigenstates, regardless of the initial eigenmode, or it can switch between the two states on demand, by simply controlling the winding direction. However, for multimode systems with higher-order EPs or multiple low-order EPs, the situation can be more involved, and the ability to control asymmetric-symmetric mode switching can be impeded, due to the breakdown of adiabaticity. Here we demonstrate that this difficulty can be overcome by winding around exceptional curves by additionally crossing diabolic points. We consider a four-mode PT-symmetric bosonic system as a platform for experimental realization of such a multimode switch. Our work provides alternative routes for light manipulations in non-Hermitian photonic setups. |
| 43. | Grzegorz Chimczak, Anna Kowalewska‑Kudłaszyk, Ewelina Lange, Karol Bartkiewicz, Jan Peřina Jr. The effect of thermal photons on exceptional points in coupled resonators. Scientific Reports, 13 , pp. 5859, 2023. @article{Chimczak2023, title = {The effect of thermal photons on exceptional points in coupled resonators.}, author = {Grzegorz Chimczak and Anna Kowalewska‑Kudłaszyk and Ewelina Lange and Karol Bartkiewicz and Jan Peřina Jr.}, url = {https://www.nature.com/articles/s41598-023-32864-2}, doi = {https://doi.org/10.1038/s41598-023-32864-2}, year = {2023}, date = {2023-04-11}, journal = {Scientific Reports}, volume = {13}, pages = {5859}, abstract = {We analyse two quantum systems with hidden parity-time ( PT ) symmetry: one is an optical device, whereas another is a superconducting microwave-frequency device. To investigate their symmetry, we introduce a damping frame (DF), in which loss and gain terms for a given Hamiltonian are balanced. We show that the non-Hermitian Hamiltonians of both systems can be tuned to reach an exceptional point (EP), i.e., the point in parameter space at which a transition from broken to unbroken hidden PT symmetry takes place. We calculate a degeneracy of a Liouvillian superoperator, which is called the Liouvillian exceptional point (LEP), and show that, in the optical domain, LEP is equivalent to EP obtained from the non-Hermitian Hamiltonian (HEP). We also report breaking the equivalence between LEP and HEP by a non-zero number of thermal photons for the microwave-frequency system.}, keywords = {}, pubstate = {published}, tppubtype = {article} } We analyse two quantum systems with hidden parity-time ( PT ) symmetry: one is an optical device, whereas another is a superconducting microwave-frequency device. To investigate their symmetry, we introduce a damping frame (DF), in which loss and gain terms for a given Hamiltonian are balanced. We show that the non-Hermitian Hamiltonians of both systems can be tuned to reach an exceptional point (EP), i.e., the point in parameter space at which a transition from broken to unbroken hidden PT symmetry takes place. We calculate a degeneracy of a Liouvillian superoperator, which is called the Liouvillian exceptional point (LEP), and show that, in the optical domain, LEP is equivalent to EP obtained from the non-Hermitian Hamiltonian (HEP). We also report breaking the equivalence between LEP and HEP by a non-zero number of thermal photons for the microwave-frequency system. |
| 42. | Jolanta Natalia Latosińska, Magdalena Latosińska, Janez Seliger, Veselko Žagar, Tomaž Apih, Paweł Grieb Molecules, 28 (8), 2023, ISSN: 1420-3049. @article{molecules28083308, title = {Elucidating the Role of Noncovalent Interactions in Favipiravir, a Drug Active against Various Human RNA Viruses; a 1H-14N NQDR/Periodic DFT/QTAIM/RDS/3D Hirshfeld Surfaces Combined Study}, author = {Jolanta Natalia Latosińska and Magdalena Latosińska and Janez Seliger and Veselko Žagar and Tomaž Apih and Paweł Grieb}, url = {https://www.mdpi.com/1420-3049/28/8/3308}, doi = {10.3390/molecules28083308}, issn = {1420-3049}, year = {2023}, date = {2023-04-07}, journal = {Molecules}, volume = {28}, number = {8}, abstract = {Favipiravir (6-fluoro-3-hydroxypyrazine-2-carboxamide, FPV), an active pharmaceutical component of the drug discovered and registered in March 2014 in Japan under the name Avigan, with an indication for pandemic influenza, has been studied. The study of this compound was prompted by the idea that effective processes of recognition and binding of FPV to the nucleic acid are affected predominantly by the propensity to form intra- and intermolecular interactions. Three nuclear quadrupole resonance experimental techniques, namely 1H-14N cross-relaxation, multiple frequency sweeps, and two-frequency irradiation, followed by solid-state computational modelling (density functional theory supplemented by the quantum theory of atoms in molecules, 3D Hirshfeld Surfaces, and reduced density gradient) approaches were applied. The complete NQR spectrum consisting of nine lines indicating the presence of three chemically inequivalent nitrogen sites in the FPV molecule was detected, and the assignment of lines to particular sites was performed. The description of the nearest vicinity of all three nitrogen atoms was used to characterize the nature of the intermolecular interactions from the perspective of the local single atoms and to draw some conclusions on the nature of the interactions required for effective recognition and binding. The propensity to form the electrostatic N−H···O, N−H···N, and C−H···O intermolecular hydrogen bonds competitive with two intramolecular hydrogen bonds, strong O−H···O and very weak N−H···N, closing the 5-member ring and stiffening the structure, as well as π···π and F···F dispersive interactions, were analysed in detail. The hypothesis regarding the similarity of the interaction pattern in the solid and the RNA template was verified. It was discovered that the -NH2 group in the crystal participates in intermolecular hydrogen bonds N–H···N and N–H···O, in the precatalytic state only in N–H···O, while in the active state in N–H···N and N–H···O hydrogen bonds, which is of importance to link FVP to the RNA template. Our study elucidates the binding modes of FVP (in crystal, precatalytic, and active forms) in detail and should guide the design of more potent analogues targeting SARS-CoV-2. Strong direct binding of FVP-RTP to both the active site and cofactor discovered by us suggests a possible alternative, allosteric mechanism of FVP action, which may explain the scattering of the results of clinical trials or the synergistic effect observed in combined treatment against SARS-CoV-2.}, keywords = {}, pubstate = {published}, tppubtype = {article} } Favipiravir (6-fluoro-3-hydroxypyrazine-2-carboxamide, FPV), an active pharmaceutical component of the drug discovered and registered in March 2014 in Japan under the name Avigan, with an indication for pandemic influenza, has been studied. The study of this compound was prompted by the idea that effective processes of recognition and binding of FPV to the nucleic acid are affected predominantly by the propensity to form intra- and intermolecular interactions. Three nuclear quadrupole resonance experimental techniques, namely 1H-14N cross-relaxation, multiple frequency sweeps, and two-frequency irradiation, followed by solid-state computational modelling (density functional theory supplemented by the quantum theory of atoms in molecules, 3D Hirshfeld Surfaces, and reduced density gradient) approaches were applied. The complete NQR spectrum consisting of nine lines indicating the presence of three chemically inequivalent nitrogen sites in the FPV molecule was detected, and the assignment of lines to particular sites was performed. The description of the nearest vicinity of all three nitrogen atoms was used to characterize the nature of the intermolecular interactions from the perspective of the local single atoms and to draw some conclusions on the nature of the interactions required for effective recognition and binding. The propensity to form the electrostatic N−H···O, N−H···N, and C−H···O intermolecular hydrogen bonds competitive with two intramolecular hydrogen bonds, strong O−H···O and very weak N−H···N, closing the 5-member ring and stiffening the structure, as well as π···π and F···F dispersive interactions, were analysed in detail. The hypothesis regarding the similarity of the interaction pattern in the solid and the RNA template was verified. It was discovered that the -NH2 group in the crystal participates in intermolecular hydrogen bonds N–H···N and N–H···O, in the precatalytic state only in N–H···O, while in the active state in N–H···N and N–H···O hydrogen bonds, which is of importance to link FVP to the RNA template. Our study elucidates the binding modes of FVP (in crystal, precatalytic, and active forms) in detail and should guide the design of more potent analogues targeting SARS-CoV-2. Strong direct binding of FVP-RTP to both the active site and cofactor discovered by us suggests a possible alternative, allosteric mechanism of FVP action, which may explain the scattering of the results of clinical trials or the synergistic effect observed in combined treatment against SARS-CoV-2. |
| 41. | Alberto Mercurio, Shilan Abo, Fabio Mauceri, Enrico Russo, Vincenzo Macrì, Adam Miranowicz, Salvatore Savasta, Omar Di Stefano Pure Dephasing of Light-Matter Systems in the Ultrastrong and Deep-Strong Coupling Regimes Phys. Rev. Lett., 130 , pp. 123601, 2023. @article{Mercurio2023, title = {Pure Dephasing of Light-Matter Systems in the Ultrastrong and Deep-Strong Coupling Regimes}, author = {Alberto Mercurio and Shilan Abo and Fabio Mauceri and Enrico Russo and Vincenzo Macrì and Adam Miranowicz and Salvatore Savasta and Omar Di Stefano}, url = {https://link.aps.org/doi/10.1103/PhysRevLett.130.123601}, doi = {10.1103/PhysRevLett.130.123601}, year = {2023}, date = {2023-03-21}, journal = {Phys. Rev. Lett.}, volume = {130}, pages = {123601}, abstract = {Pure dephasing originates from the nondissipative information exchange between quantum systems and environments, and plays a key role in both spectroscopy and quantum information technology. Often pure dephasing constitutes the main mechanism of decay of quantum correlations. Here we investigate how pure dephasing of one of the components of a hybrid quantum system affects the dephasing rate of the system transitions. We find that, in turn, the interaction, in the case of a light-matter system, can significantly affect the form of the stochastic perturbation describing the dephasing of a subsystem, depending on the adopted gauge. Neglecting this issue can lead to wrong and unphysical results when the interaction becomes comparable to the bare resonance frequencies of subsystems, which correspond to the ultrastrong and deep-strong coupling regimes. We present results for two prototypical models of cavity quantun electrodynamics: the quantum Rabi and the Hopfield model.}, keywords = {}, pubstate = {published}, tppubtype = {article} } Pure dephasing originates from the nondissipative information exchange between quantum systems and environments, and plays a key role in both spectroscopy and quantum information technology. Often pure dephasing constitutes the main mechanism of decay of quantum correlations. Here we investigate how pure dephasing of one of the components of a hybrid quantum system affects the dephasing rate of the system transitions. We find that, in turn, the interaction, in the case of a light-matter system, can significantly affect the form of the stochastic perturbation describing the dephasing of a subsystem, depending on the adopted gauge. Neglecting this issue can lead to wrong and unphysical results when the interaction becomes comparable to the bare resonance frequencies of subsystems, which correspond to the ultrastrong and deep-strong coupling regimes. We present results for two prototypical models of cavity quantun electrodynamics: the quantum Rabi and the Hopfield model. |
| 40. | Andrzej Grudka, Marcin Karczewski, Paweł Kurzyński, Jan Wójcik, Antoni Wójcik Topological invariants in quantum walks Physical Review A, 107 , pp. 032201, 2023. @article{grudka23, title = {Topological invariants in quantum walks}, author = {Andrzej Grudka and Marcin Karczewski and Paweł Kurzyński and Jan Wójcik and Antoni Wójcik}, doi = {10.1103/PhysRevA.107.032201}, year = {2023}, date = {2023-03-01}, journal = {Physical Review A}, volume = {107}, pages = {032201}, abstract = {Discrete-time quantum walks (DTQWs) provide a convenient platform for a realization of many topological phases in noninteracting systems. They often offer more possibilities than systems with a static Hamiltonian. Nevertheless, researchers are still looking for DTQW symmetries protecting topological phases and for definitions of appropriate topological invariants. Although the majority of DTQW studies on this topic focus on the so-called split-step quantum walk, two distinct topological phases can be observed in more basic models. Here we infer topological properties of the basic DTQWs directly from the mapping of the Brillouin zone to the Bloch Hamiltonian. We show that for translation-symmetric systems they can be characterized by a homotopy relative to special points. We also propose a topological invariant corresponding to this concept. This invariant indicates the number of edge states at the interface between two distinct phases.}, keywords = {}, pubstate = {published}, tppubtype = {article} } Discrete-time quantum walks (DTQWs) provide a convenient platform for a realization of many topological phases in noninteracting systems. They often offer more possibilities than systems with a static Hamiltonian. Nevertheless, researchers are still looking for DTQW symmetries protecting topological phases and for definitions of appropriate topological invariants. Although the majority of DTQW studies on this topic focus on the so-called split-step quantum walk, two distinct topological phases can be observed in more basic models. Here we infer topological properties of the basic DTQWs directly from the mapping of the Brillouin zone to the Bloch Hamiltonian. We show that for translation-symmetric systems they can be characterized by a homotopy relative to special points. We also propose a topological invariant corresponding to this concept. This invariant indicates the number of edge states at the interface between two distinct phases. |
| 39. | Kuan-Yi Lee, Jhen-Dong Lin, Adam Miranowicz, Franco Nori, Huan-Yu Ku, Yueh-Nan Chen Steering-enhanced quantum metrology using superpositions of noisy phase shifts Phys. Rev. Res., 5 , pp. 013103, 2023. @article{23prr-lee, title = {Steering-enhanced quantum metrology using superpositions of noisy phase shifts}, author = {Kuan-Yi Lee and Jhen-Dong Lin and Adam Miranowicz and Franco Nori and Huan-Yu Ku and Yueh-Nan Chen}, url = {https://link.aps.org/doi/10.1103/PhysRevResearch.5.013103}, doi = {10.1103/PhysRevResearch.5.013103}, year = {2023}, date = {2023-02-13}, journal = {Phys. Rev. Res.}, volume = {5}, pages = {013103}, publisher = {American Physical Society}, abstract = {Quantum steering is an important correlation in quantum information theory. A recent work [Nat. Commun. 12, 2410 (2021)] showed that quantum steering is also useful for quantum metrology. Here, we extend the exploration of steering-enhanced quantum metrology from single noiseless phase shifts to superpositions of noisy phase shifts. As concrete examples, we consider a control system that manipulates a target system to pass through a superposition of either dephased or depolarized phase shifts channels. We show that using such superpositions of noisy phase shifts can suppress the effects of noise and improve metrology. Furthermore, we also implemented proof-of-principle experiments for a superposition of dephased phase shifts on the IBM quantum experience, demonstrating a clear improvement on metrology.}, keywords = {}, pubstate = {published}, tppubtype = {article} } Quantum steering is an important correlation in quantum information theory. A recent work [Nat. Commun. 12, 2410 (2021)] showed that quantum steering is also useful for quantum metrology. Here, we extend the exploration of steering-enhanced quantum metrology from single noiseless phase shifts to superpositions of noisy phase shifts. As concrete examples, we consider a control system that manipulates a target system to pass through a superposition of either dephased or depolarized phase shifts channels. We show that using such superpositions of noisy phase shifts can suppress the effects of noise and improve metrology. Furthermore, we also implemented proof-of-principle experiments for a superposition of dephased phase shifts on the IBM quantum experience, demonstrating a clear improvement on metrology. |
| 38. | Marceli Koralewski, Małgorzata Paprzycka Journal of Molecular Liquids, 375 , pp. 121375, 2023. @article{Koralewski2023, title = {Faraday effect and refractive index of some imidazolium-based room-temperature ionic liquids and magnetic ionic liquids}, author = {Marceli Koralewski and Małgorzata Paprzycka}, doi = {10.1016/j.molliq.2023.121375}, year = {2023}, date = {2023-02-02}, journal = {Journal of Molecular Liquids}, volume = {375}, pages = {121375}, abstract = {Knowledge of the Faraday effect (FE) is very important in fundamental research and applications. Here, we report FE and refractive index studies for two magnetic ionic liquids (MILs), namely 1-ethyl- and 1-butyl-3-methylimidazolium tetrachloroferrate. Similar studies are also conducted for ionic liquids (ILs) that have a diamagnetic counteranion in place of [FeCl4]. The magnitudes of the Verdet constants of MILs are comparable and exhibit a negative sign. Furthermore, they are about one order larger than those of ILs with a diamagnetic counteranion of a positive sign. The Verdet constant shows monotonic variations as a function of wavelength in the range from 450 to 650 nm and is mainly related to charge transfer transitions in [FeCl4], with bands located in the UV region, though the contribution of d-d transitions in Fe+3 is negligible. A model for describing the measured Verdet constant data as a function of wavelength and temperature is given with respective values of effective Faraday A-, B-, and D-terms. The introduction of an empirical rule allows the estimation of Verdet constants of iron and imidazolium derivative based MILs, which are in some cases very high, thus indicating their potential in photonics applications. Imidazole shows a positive and nearly-two orders lower magnitude of the Verdet constant. The mixture of an MIL and acetonitrile allows the tuning of both the Verdet constant and the refractive index. The refractive indices, thermo-optic coefficients, and electronic polarizabilities of MILs are higher than those of ILs with a diamagnetic counteranion.}, keywords = {}, pubstate = {published}, tppubtype = {article} } Knowledge of the Faraday effect (FE) is very important in fundamental research and applications. Here, we report FE and refractive index studies for two magnetic ionic liquids (MILs), namely 1-ethyl- and 1-butyl-3-methylimidazolium tetrachloroferrate. Similar studies are also conducted for ionic liquids (ILs) that have a diamagnetic counteranion in place of [FeCl4]. The magnitudes of the Verdet constants of MILs are comparable and exhibit a negative sign. Furthermore, they are about one order larger than those of ILs with a diamagnetic counteranion of a positive sign. The Verdet constant shows monotonic variations as a function of wavelength in the range from 450 to 650 nm and is mainly related to charge transfer transitions in [FeCl4], with bands located in the UV region, though the contribution of d-d transitions in Fe+3 is negligible. A model for describing the measured Verdet constant data as a function of wavelength and temperature is given with respective values of effective Faraday A-, B-, and D-terms. The introduction of an empirical rule allows the estimation of Verdet constants of iron and imidazolium derivative based MILs, which are in some cases very high, thus indicating their potential in photonics applications. Imidazole shows a positive and nearly-two orders lower magnitude of the Verdet constant. The mixture of an MIL and acetonitrile allows the tuning of both the Verdet constant and the refractive index. The refractive indices, thermo-optic coefficients, and electronic polarizabilities of MILs are higher than those of ILs with a diamagnetic counteranion. |
| 37. | Jolanta Natalia Latosińska, Magdalena Latosińska, Andrzei Orzeszko, Jan Krzysztof Maurin Molecules, 28 (1), pp. 147, 2023. @article{Latosińska2023, title = {Synthesis and Crystal Structure of Adamantylated 4,5,6,7-tetrahalogeno-1H-benzimidazoles Novel Multi-Target Ligands (Potential CK2, M2 and SARS-CoV-2 Inhibitors). X-ray/DFT/QTAIM/Hirshfeld Surfaces/Molecular Docking Study }, author = {Jolanta Natalia Latosińska and Magdalena Latosińska and Andrzei Orzeszko and Jan Krzysztof Maurin }, doi = {10.3390/molecules28010147}, year = {2023}, date = {2023-01-02}, journal = {Molecules}, volume = {28}, number = {1}, pages = {147}, abstract = {A series of new congeners, 1-[2-(1-adamantyl)ethyl]-1H-benzimidazole (AB) and 1-[2-(1-adamantyl)ethyl]-4,5,6,7-tetrahalogeno-1H-benzimidazole (Hal=Cl, Br, I; tClAB, tBrAB, tIAB), have been synthesized and studied. These novel multi-target ligands combine a benzimidazole ring known to show antitumor activity and an adamantyl moiety showing anti-influenza activity. Their crystal structures were determined by X-ray, while intermolecular interactions were studied using topological Bader’s Quantum Theory of Atoms in Molecules, Hirshfeld Surfaces, CLP and PIXEL approaches. The newly synthesized compounds crystallize within two different space groups, P-1 (AB and tIAB) and P21/c (tClAB and tBrAB). A number of intramolecular hydrogen bonds, C−H⋯Hal (Hal=Cl, Br, I), were found in all halogen-containing congeners studied, but the intermolecular C−H⋯N hydrogen bond was detected only in AB and tIAB, while C−Hal⋯π only in tClAB and tBrAB. The interplay between C−H⋯N and C−H⋯Hal hydrogen bonds and a shift from the strong (C−H⋯Cl) to the very weak (C−H⋯I) attractive interactions upon Hal exchange, supplemented with Hal⋯Hal overlapping, determines the differences in the symmetry of crystalline packing and is crucial from the biological point of view. The hypothesis about the potential dual inhibitor role of the newly synthesized congeners was verified using molecular docking and the congeners were found to be pharmaceutically attractive as Human Casein Kinase 2, CK2, inhibitors, Membrane Matrix 2 Protein, M2, blockers and Severe Acute Respiratory Syndrome Coronavirus 2, SARS-CoV-2, inhibitors. The addition of adamantyl moiety seems to broaden and modify the therapeutic indices of the 4,5,6,7-tetrahalogeno-1H-benzimidazoles.}, keywords = {}, pubstate = {published}, tppubtype = {article} } A series of new congeners, 1-[2-(1-adamantyl)ethyl]-1H-benzimidazole (AB) and 1-[2-(1-adamantyl)ethyl]-4,5,6,7-tetrahalogeno-1H-benzimidazole (Hal=Cl, Br, I; tClAB, tBrAB, tIAB), have been synthesized and studied. These novel multi-target ligands combine a benzimidazole ring known to show antitumor activity and an adamantyl moiety showing anti-influenza activity. Their crystal structures were determined by X-ray, while intermolecular interactions were studied using topological Bader’s Quantum Theory of Atoms in Molecules, Hirshfeld Surfaces, CLP and PIXEL approaches. The newly synthesized compounds crystallize within two different space groups, P-1 (AB and tIAB) and P21/c (tClAB and tBrAB). A number of intramolecular hydrogen bonds, C−H⋯Hal (Hal=Cl, Br, I), were found in all halogen-containing congeners studied, but the intermolecular C−H⋯N hydrogen bond was detected only in AB and tIAB, while C−Hal⋯π only in tClAB and tBrAB. The interplay between C−H⋯N and C−H⋯Hal hydrogen bonds and a shift from the strong (C−H⋯Cl) to the very weak (C−H⋯I) attractive interactions upon Hal exchange, supplemented with Hal⋯Hal overlapping, determines the differences in the symmetry of crystalline packing and is crucial from the biological point of view. The hypothesis about the potential dual inhibitor role of the newly synthesized congeners was verified using molecular docking and the congeners were found to be pharmaceutically attractive as Human Casein Kinase 2, CK2, inhibitors, Membrane Matrix 2 Protein, M2, blockers and Severe Acute Respiratory Syndrome Coronavirus 2, SARS-CoV-2, inhibitors. The addition of adamantyl moiety seems to broaden and modify the therapeutic indices of the 4,5,6,7-tetrahalogeno-1H-benzimidazoles. |
| 36. | Jan Wójcik, Grzegorz Chimczak Electrically coupled optomechanical cavities as a tool for quantum nondemolition measurement Physics Letters A, 490 , pp. 129187, 2023, ISSN: 0375-9601. @article{WOJCIK2023129187, title = {Electrically coupled optomechanical cavities as a tool for quantum nondemolition measurement}, author = {Jan Wójcik and Grzegorz Chimczak}, url = {https://www.sciencedirect.com/science/article/pii/S0375960123005674}, doi = {https://doi.org/10.1016/j.physleta.2023.129187}, issn = {0375-9601}, year = {2023}, date = {2023-01-01}, journal = {Physics Letters A}, volume = {490}, pages = {129187}, abstract = {We present a new model of two electrically coupled optomechanical cavities. This model is based on the recently presented proposal [Physical Review A 103 (2021) 043509]. We found that coupling two optomechanical cavities via Coulomb force leads to cross-Kerr interactions between those cavities. We show that such systems may be ideal for a protocol of quantum non-demolition measurement because it is easy to eliminate the self-phase modulation effect. Moreover, nonlinearities in our model are based on easily adjustable parameters, and therefore, given recent experimental studies, we believe that experimental realization of a cross-Kerr interaction via Coulomb force coupling is feasible.}, keywords = {}, pubstate = {published}, tppubtype = {article} } We present a new model of two electrically coupled optomechanical cavities. This model is based on the recently presented proposal [Physical Review A 103 (2021) 043509]. We found that coupling two optomechanical cavities via Coulomb force leads to cross-Kerr interactions between those cavities. We show that such systems may be ideal for a protocol of quantum non-demolition measurement because it is easy to eliminate the self-phase modulation effect. Moreover, nonlinearities in our model are based on easily adjustable parameters, and therefore, given recent experimental studies, we believe that experimental realization of a cross-Kerr interaction via Coulomb force coupling is feasible. |
| 35. | Marceli Koralewski, Małgorzata Paprzycka, Alice Goyal, Krzysztof Gibasiewicz Faraday rotation enhancement for colloidal spherical Au and Ag nanoparticles and their mixtures Journal of Magnetism and Magnetic Materials, 588 , pp. 171461, 2023, ISSN: 0304-8853. @article{Koralewski2023b, title = {Faraday rotation enhancement for colloidal spherical Au and Ag nanoparticles and their mixtures}, author = {Marceli Koralewski and Małgorzata Paprzycka and Alice Goyal and Krzysztof Gibasiewicz}, url = {http://dx.doi.org/10.1016/j.jmmm.2023.171461}, doi = {10.1016/j.jmmm.2023.171461}, issn = {0304-8853}, year = {2023}, date = {2023-01-01}, journal = {Journal of Magnetism and Magnetic Materials}, volume = {588}, pages = {171461}, publisher = {Elsevier BV}, keywords = {}, pubstate = {published}, tppubtype = {article} } |
| 34. | Marceli Koralewski, Małgorzata Paprzycka, Katarina Siposova, Oskar Sobotka The kinetics of aggregation of the Aβ1-40 peptide monitored by magnetooptical methods Journal of Magnetism and Magnetic Materials, 587 , pp. 171273, 2023, ISSN: 0304-8853. @article{Koralewski2023c, title = {The kinetics of aggregation of the Aβ1-40 peptide monitored by magnetooptical methods}, author = {Marceli Koralewski and Małgorzata Paprzycka and Katarina Siposova and Oskar Sobotka}, url = {http://dx.doi.org/10.1016/j.jmmm.2023.171273}, doi = {10.1016/j.jmmm.2023.171273}, issn = {0304-8853}, year = {2023}, date = {2023-01-01}, journal = {Journal of Magnetism and Magnetic Materials}, volume = {587}, pages = {171273}, publisher = {Elsevier BV}, keywords = {}, pubstate = {published}, tppubtype = {article} } |
2022 |
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| 33. | Ye-Hong Chen, Adam Miranowicz, Xi Chen, Yan Xia, Franco Nori Enhanced-Fidelity Ultrafast Geometric Quantum Computation Using Strong Classical Drives Phys. Rev. Appl., 18 , pp. 064059, 2022. @article{Chen22geom, title = {Enhanced-Fidelity Ultrafast Geometric Quantum Computation Using Strong Classical Drives}, author = {Ye-Hong Chen and Adam Miranowicz and Xi Chen and Yan Xia and Franco Nori}, url = {https://link.aps.org/doi/10.1103/PhysRevApplied.18.064059}, doi = {10.1103/PhysRevApplied.18.064059}, year = {2022}, date = {2022-12-20}, journal = {Phys. Rev. Appl.}, volume = {18}, pages = {064059}, publisher = {American Physical Society}, abstract = {We propose a general approach to implement ultrafast nonadiabatic geometric single- and two-qubit gates by employing counter-rotating effects. This protocol is compatible with most optimal control methods used in previous rotating-wave approximation (RWA) protocols; thus, it is as robust as (or even more robust than) the RWA protocols. Using counter-rotating effects allows us to apply strong drives. Therefore, we can improve the gate speed by 5–10 times compared to the RWA counterpart for implementing high-fidelity (≥99.99%) gates. Such an ultrafast evolution (nanoseconds, even picoseconds) significantly reduces the influence of decoherence (e.g., the qubit dissipation and dephasing). Moreover, because the counter-rotating effects no longer induce a gate infidelity (in both the weak and strong driving regimes), we can achieve a higher fidelity compared to the RWA protocols. Therefore, in the presence of decoherence, one can implement ultrafast geometric quantum gates with ≥99% fidelities.}, keywords = {}, pubstate = {published}, tppubtype = {article} } We propose a general approach to implement ultrafast nonadiabatic geometric single- and two-qubit gates by employing counter-rotating effects. This protocol is compatible with most optimal control methods used in previous rotating-wave approximation (RWA) protocols; thus, it is as robust as (or even more robust than) the RWA protocols. Using counter-rotating effects allows us to apply strong drives. Therefore, we can improve the gate speed by 5–10 times compared to the RWA counterpart for implementing high-fidelity (≥99.99%) gates. Such an ultrafast evolution (nanoseconds, even picoseconds) significantly reduces the influence of decoherence (e.g., the qubit dissipation and dephasing). Moreover, because the counter-rotating effects no longer induce a gate infidelity (in both the weak and strong driving regimes), we can achieve a higher fidelity compared to the RWA protocols. Therefore, in the presence of decoherence, one can implement ultrafast geometric quantum gates with ≥99% fidelities. |
| 32. | Jan Perina Jr, Adam Miranowicz, Grzegorz Chimczak, Anna Kowalewska-Kudłaszyk Quantum, 6 , pp. 883, 2022, ISSN: 2521-327X. @article{Perina2022quantum, title = {Quantum Liouvillian exceptional and diabolical points for bosonic fields with quadratic Ħamiltonians: Ŧhe Ħeisenberg-Langevin equation approach}, author = {Jan Perina Jr and Adam Miranowicz and Grzegorz Chimczak and Anna Kowalewska-Kudłaszyk}, url = {https://doi.org/10.22331/q-2022-12-22-883}, doi = {10.22331/q-2022-12-22-883}, issn = {2521-327X}, year = {2022}, date = {2022-12-10}, journal = {Quantum}, volume = {6}, pages = {883}, publisher = {Verein zur Förderung des Open Access Publizierens in den Quantenwissenschaften}, abstract = {Equivalent approaches to determine eigenfrequencies of the Liouvillians of open quantum systems are discussed using the solution of the Heisenberg-Langevin equations and the corresponding equations for operator moments. A simple damped two-level atom is analyzed to demonstrate the equivalence of both approaches. The suggested method is used to reveal the structure as well as eigenfrequencies of the dynamics matrices of the corresponding equations of motion and their degeneracies for interacting bosonic modes described by general quadratic Hamiltonians. Quantum Liouvillian exceptional and diabolical points and their degeneracies are explicitly discussed for the case of two modes. Quantum hybrid diabolical exceptional points (inherited, genuine, and induced) and hidden exceptional points, which are not recognized directly in amplitude spectra, are observed. The presented approach via the Heisenberg-Langevin equations paves the general way to a detailed analysis of quantum exceptional and diabolical points in infinitely dimensional open quantum systems.}, keywords = {}, pubstate = {published}, tppubtype = {article} } Equivalent approaches to determine eigenfrequencies of the Liouvillians of open quantum systems are discussed using the solution of the Heisenberg-Langevin equations and the corresponding equations for operator moments. A simple damped two-level atom is analyzed to demonstrate the equivalence of both approaches. The suggested method is used to reveal the structure as well as eigenfrequencies of the dynamics matrices of the corresponding equations of motion and their degeneracies for interacting bosonic modes described by general quadratic Hamiltonians. Quantum Liouvillian exceptional and diabolical points and their degeneracies are explicitly discussed for the case of two modes. Quantum hybrid diabolical exceptional points (inherited, genuine, and induced) and hidden exceptional points, which are not recognized directly in amplitude spectra, are observed. The presented approach via the Heisenberg-Langevin equations paves the general way to a detailed analysis of quantum exceptional and diabolical points in infinitely dimensional open quantum systems. |